As the production process continues to be refined, biomass pyrolysis oils are increasingly being considered as potentially feasible renewable fuels. Combustion of pyrolysis oils in diesel engines has been scarcely studied, and the few studies which have been performed indicate that these fuels exhibit excessively long ignition delay, rendering them dependant on auxiliary ignition sources for di...

This paper presents the results of three-dimensional and time-accurate Computational Fluid Dynamics (CFD) simulations of the flow field around the National Renewable Energy Laboratory (NREL) Phase VI horizontal axis wind turbine rotor. The 3-D, unsteady, parallel, finite volume flow solver, PUMA2, is used for the simulations. The solutions are obtained using unstructured moving grids rotating w...

A computational investigation of the high-pressure phase sequence of the heaviest alkali hydroxides, RbOH and CsOH, shows that the phase diagram of both compounds is richer than hitherto thought. First-principles calculations suggest, based on energetics and comparisons to experimental diffraction and spectroscopy signatures, that the high-pressure phase RbOH-VI, stable above 6 GPa in experimen...

BACKGROUND Typhoid fever causes more than 21 million cases of disease and 200,000 deaths yearly worldwide, with more than 90% of the disease burden being reported from Asia. Epidemiological data show high disease incidence in young children and suggest that immunization programs should target children below two years of age: this is not possible with available vaccines. The Novartis Vaccines In...

Crown ethers 12-crown-4 (12C4), benzo-15-crown-5 (B15C5), 18-crown-6 (18C6), nitrobenzo-18-crown-6 (NB18C6) dibenzo-18-crown-6 (DB18C6) and dicyclohexyl-18-crown-6 (DC18C6), dissolved in dichloromethane, are able to form oxonium-ion complexes in contact with aqueous sulfuric and hydrochloric acid solutions. This ability allows the transfer of Cr(VI) oxanions from the acid media, through an ...

Gas-phase plutonium nitrate anion complexes were produced by electrospray ionization (ESI) of a plutonium nitrate solution. The ESI mass spectrum included species with all four of the common oxidation states of plutonium: Pu(III), Pu(IV), Pu(V), and Pu(VI). Plutonium nitrate complexes were isolated in a quadrupole ion trap and subjected to collision-induced dissociation (CID). CID of complexes ...

FUSE observations were obtained in July 2003 during 1.2 cycles of the 0.76-day binary orbit of RX J0513.9−6951. Radial velocity measurements of the broad O VI emission profile show a semiamplitude of K∼26 km s −1 , which is much smaller than the value of 117 km s −1 measured from 2001 FUSE data. Narrow O VI emissions show no measurable velocity variation. The mean velocity of the broad O VI emi...

Phase VI of bis-(tetra-methyl-ammonium) tetra-chloro-zincate(II), (C(4)H(12)N)(2)[ZnCl(4)], contains three formula units per asymmetric unit. Several short C-H⋯Cl contacts [2.70 (3) and 2.72 (4) Å] are observed, but they are believed to participate only in van der Waals inter-actions. The crystal studied exhibited inversion twinning.