In the present study, selected metal ions (M = Cr, Mn, Co, Ni, Cu, Zn, and Ce) were introduced into iron oxide (spinel lattice) and screened for effectiveness for a high-temperature water–gas shift reaction. Simultaneous precipitation of Fe(III) nitrates along with metal nitrate(s) at optimal concentrations resulted in the formation of high-surface area nanosized catalysts. A noticeable interac...

Because of its strong pollutant degradation ability, nanoscale zerovalent iron (NZVI) has been introduced to soils and groundwater for remediation purposes, but its impacts on plants are still not very clear. In this work, the effects of low concentration (10-320 μmol/L) NZVI particles on seed germination and growth of peanut plants were evaluated. The exposure of peanut seeds to NZVI at all th...

Introduction: Recent TEM studies revealed that Fe-Ni metal nano-particles are responsible for the dark “brown” color of olivine in the NWA2737 chassignite, which is interpreted to have formed by reduction of olivine due to heavy shock events [1,2]. Color change of olivine is important to understand the remote sensing data as is the case for space weathering [3,4]. Furthermore, nano-phase Fe par...

We put forward the quantum screening effect in field emission [FE] nanodiodes, explaining relatively low field enhancement factors due to the increased potential barrier that impedes the electron Fowler-Nordheim tunneling, which is usually observed in nanoscale FE experiments. We illustratively show this effect from the energy band diagram and experimentally verify it by performing the nanomani...

Nanoscale surface corrugation strongly determines the plasmonic response of gold nanoparticles with dimensions of several tens of nanometres. Scattering spectra of individual spheres with a rough surface were found to red-shift and broaden. The plasmon modes exhibited quadrupole damping, in contrast to particles with smooth surfaces. Additionally, rougher spheres display a higher SERS activity,...

A new technique for nanoparticle sizing that allows visualisation of nanoscale particles in liquids on an individual basis is described. The technology comprises a metallised optical element illuminated by laser beam at the surface of which nanoscale particles in suspension can be directly visualised, sized and counted in real time using only a conventional optical microscope fitted with a low ...

Abstract The dynamic field emission of a carbon nanotube at mechanical resonance has been studied by in situ transmission electron microscopy. The coupling between the field emission (FE) of a nanotube under a dc voltage applied longitudinally and its mechanical resonance stimulated transversely by an ac field shows that the frequency of the FE oscillating current is twice that of the mechanica...

Trapping and manipulation of microscale and nanoscale particles is demonstrated using the sole action of hydrodynamic forces. We developed an automated particle trap based on a stagnation point flow generated in a microfluidic device. The hydrodynamic trap enables confinement and manipulation of single particles in low viscosity (1-10 cP) aqueous solution. Using this method, we trapped microsca...

Submitted for the MAR16 Meeting of The American Physical Society Fe-catalyzed etching of graphene layers GUANGJUN CHENG, IRENE CALIZO, ANGELA HIGHT WALKER, NIST, PML, NIST TEAM — We investigate the Fe-catalyzed etching of graphene layers in forming gas. Fe thin films are deposited by sputtering onto mechanically exfoliated graphene, few-layer graphene (FLG), and graphite flakes on a Si/SiO2 sub...

Nanoscale thermites such as the composite mixture of nano-sized aluminum and molybdenum trioxide powders possess several technical advantages such as much higher reaction rate and shorter ignition delay, when compared to the conventional energetic formulations made of micron-sized metal and oxidizer particles. In this study, the self-propagation of combustion wave in compacted pellets of nanosc...