Pseudomonas putida for H2S and Arthrobacter oxydans for NH3 were immobilized with Ca-alginate and packed inside glass columns to form fluidized-bed bioreactors. The feasibility of the lab-scale bioreactor for the treatment of H2S or NH3 was examined. Phosphate salt, being added to the nutrient solution as buffer solution, may chelate with Ca2+ in the Ca-alginate beads, resulting in the disinteg...

The formation of small ammonia clusters is investigated experimentally with a supersonic free molecular jet of NH3−X binary mixtures (X = Ar, He, N2), with a special attention paid to the effect of second species X on the cluster formation. The ion currents of protonated ammonia clusters (NH3)nH + (n = 2−6) were measured with a combined cluster source system and a double focussing sector field ...

this study was carried out to investigate the effects of treated protein supplements with tannin extracted from pistachio by-product (p-pb) on in vitro gas production using fistulated sheep. one portion of p-pb was mixed with four portions of water for 48 h. the extracted product was sprayed on soybean meal (sbm) or canola meal (cm) with an equal ratio (1:1 v/w) and dried in the shade. the expe...

Superalkali Li3 dissolved in gaseous ammonia is investigated by density functional theory. Similar to the lithium atom, Li3 can coordinate up to four ammonia molecules. Among the structural isomers of Li3(NH3)n (n = 1-4), the one with separately distributed NH3 ligands is preferred. Most of the Li3(NH3)n species possess the alkalide characteristics and exhibit considerably large static first hy...

Quantification of aerial emissions from animal feeding operations (AFOs) requires the knowledge of both concentration of the constituent of interest and the ventilation rate (VR) through the emitting source. Daily emissions can be and are normally determined from diurnal integration of frequent measurements, referred to as the diurnal integration method (DIM), but is resource intensive. Alterna...

The broiler industry is not immune to the problematic nature of NH3 production in animal rearing facilities. Though the headlines of today focus on environmental impact considerations, the detrimental effects of the house air quality on farmers and birds remain considerable for industry viability. This research investigated the vertical stratification of in-house NH3 combined with sampling posi...

Compensation points for gaseous exchange of ammonia (NH3) between stomata and the atmosphere were determined in an oilseed rape (Brassica napus) canopy by analysing the concentrations of NH4+ and H+ in leaf apoplastic solution. This bioassay approach was applied for the first time in the field, allowing the first intercomparison with compensation points derived from micrometeorological measurem...

The influence of different N sources on fermentation rate and de novo amino acid synthesis by rumen micro-organisms was investigated in vitro using rumen fluid taken from four sheep receiving a mixed diet comprising (g/kg DM): grass hay 500, barley 299.5, molasses 100, fish meal 91, minerals and vitamins 9.5. Pancreatic casein hydrolysate (P; comprising mainly peptides with some free amino acid...

Two experiments were conducted with growing male rats to determine the effects of 120 ppm of dietary sarsaponin (S) on nitrogen (N) metabolism when urea or protein are added to the diet. Growth, feed efficiency, N digestibility and balance, urinary N and ammonia-N (NH3-N), and cecal urease and NH3-N were measured. Growth and feed utilization were unaffected by dietary S. Adding urea or protein ...

we have performed density functional theory investigations on the adsorption properties of ammonia molecule on the undoped and n-doped tio2 anatase nanoparticles. we have geometrically optimized the constructed undoped and n-doped nanoparticles in order to fully understand the adsorption behaviors of ammonia molecule. for tio2 anatase nanoparticles, the binding site is preferentially located on...