We report a new and effective method to prepare high activity graphitic carbon nitride (g-C3N4) by a simple ammonia etching treatment. The obtained g-C3N4 displays a high BET surface area and enhanced electron/hole separation efficiency. The hydrogen evolution rates improved from 52 μmol h(-1) to 316.7 μmol h(-1) under visible light.

Graphitic carbon nitride (g-C3N4) quantum dots (CNQDs) were prepared from bulk g-C3N4 directly by a thermal-chemical etching process. The CNQDs show strong blue emission as well as upconversion behavior, which can be used as universal energy-transfer components in visible-light-driven metal-free photocatalytic systems.

A C3N4-sensitized TiO2 nanotube array-based photoanode was designed and fabricated via the in situ growth of C3N4 on the surface of TiO2 nanotubes. It shows stable and significantly improved PEC activity for hydrogen generation under visible light irradiation with a hydrogen production rate of about 19.1 μmol h(-1) (a Faradaic efficiency of nearly 100%).

Successful synthesis of the stable metal-free two-dimensional polymer graphitic carbon-nitride with remarkable properties has made it as one of the most promising nanostructures in many novel nanodevices, especially photocatalytic ones. Understanding the mechanical properties of nanostructures is of crucial importance. Thus, this study employs density functional theory (DFT) to obtain the mecha...

g-C3N4 is a promising material for hydrogen production from water via photo-catalysis, if we can tune its band gap to desirable levels. Using a combined experimental and ab initio approach, we uncover an almost perfectly linear relationship between the band gap and structural aspects of g-C3N4, which we show to originate in a changing overlap of wave functions associated with the lattice consta...

Understanding the photoexcitation processes in semiconductors is critical for the design of advanced photocatalytic materials. Nevertheless, traditional viewpoints focus on photogenerated free charge carriers, which are somehow invalid once the many-body effects are taken into account, especially for polymeric photocatalysts. Here we systematically investigate the photoexcitation processes invo...

A novel CeO2 nanorod/g-C3N4/N-rGO ternary composite was synthesized using a simple ultrasonic-heat treatment method for application in the photocatalytic degradation of organic pollutants under the irradiation of visible light. This material shows superior photocatalytic activity compared with pure g-C3N4 and CeO2 nanorods, and the photodegradation rate of RhB is up to 2.1-fold higher than that...

The Molecules Editorial Office wishes to make the following erratum to this paper [1]. There is a misspelling in the title of “Mechanism of NO Photocatalytic Oxidationon g-C3N4 Was Changed by Pd-QDs Modification.” The correct title should be “Mechanism of NO Photocatalytic Oxidation on g-C3N4 Was Changed by Pd-QDs Modification.” We apologize for any inconvenience caused to the readers by this m...

Understanding the photoexcitation processes in semiconductors is critical for the design of advanced photocatalytic materials. Nevertheless, traditional viewpoints focus on photogenerated free charge carriers, which are somehow invalid once the many-body effects are taken into account, especially for polymeric photocatalysts. Here we systematically investigate the photoexcitation processes invo...

We propose porous C-N-based structures for biocompatible magnetic materials that do not contain even a single metal ion. Using first-principles calculations based on density functional theory, we show that when patterned in the form of a kagome lattice, nonmagnetic g-C3N4 not only becomes ferromagnetic but also its magnetic properties can be further enhanced by applying external strain. Similar...