*e-mail: [email protected] On the leave of absence from Departmento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo. Current address: Solid State Chemistry Group, Laboratoire de Physique de la Matière Condensée, Ecole Polytechnique, Université Paris-Saclay, Route de Saclay 91128 Palaiseau, France. From Lighting to Photoprotection: Fundamentals an...

We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of ortho-quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal-...

Lithium-stuffed garnets attract huge attention due to their outstanding potential as solid-state electrolytes for lithium batteries. However, there exists a persistent challenge in the reliable synthesis of these complex functional oxides together with a lack of complete understanding of the lithium-ion diffusion mechanisms in these important materials. Addressing these issues is critical to re...

Light without fright: a synthetic route to fluorescent primary phosphanes (RPH(2)) that are resistant to air oxidation both in the solid state and in chloroform solution is described. These versatile precursors undergo hydrophosphination to give tripodal ligands and subsequently fluorescent transition-metal complexes.

The structure and reactivity of a room temperature stable zinc carbonyl complex in Zn-modified H-ZSM-5 zeolite were revealed by solid-state NMR spectroscopy.

Comparing a solution phase route to a solid phase route in the synthesis of the cytotoxic natural product urukthapelstatin A (Ustat A) confirmed that a solid phase method is superior. The solution phase approach was tedious and involved cyclization of a ridged heterocyclic precursor, while solid phase allowed the rapid generation of a flexible linear peptide. Cyclization of the linear peptide w...

a simple, efficient and clean procedure has been developed for the cleavage of imines c=n bond. deprotection of imines to their parent carbonyl and amine compounds was achieved using p-toluenesulfonic acid in the solid state condition at 25-45 ˚c. the salient features of this methodology are shorter reaction times, cheap processing, high yields of product and easy availability of the catalyst. ...

optimization of the fermentation medium for maximum alkaline protease production was carried out. fifteen positive isolates were examined for their extent of alkaline protease production. the most potent producer was identified as bacillus sp. the solid substrate screening showed that the combination of wheat straw and bean husk was the best one. the initial screening by using plackett–burman’s...

copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [cu3(btc)2] (1) and [cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400,  500, and 600°c. it has also been found that the reaction temperature pla...