نتایج جستجو برای: model free isoconversional method
تعداد نتایج: 3784731 فیلتر نتایج به سال:
in this thesis a calibration transfer method is used to achieve bilinearity for augmented first order kinetic data. first, the proposed method is investigated using simulated data and next the concept is applied to experimental data. the experimental data consists of spectroscopic monitoring of the first order degradation reaction of carbaryl. this component is used for control of pests in frui...
در این تحقیق به بررسی و مقایسه تاثیر سازه های آبشکن نفوذپذیر و نفوذناپذیر بر مورفولوژی کف رودخانه در دو بعد پرداخته شده است. برای پیدا کردن روش حل عددی مناسب، مقایسه ای میان روش های بدون شبکه radial point interpolation method(rpim)، element free galerkin و روش اجزا محدود انجام شده است. نتیجه این تحقیق کارایی روش (rpim) را نسبت به سایر روش ها نشان می دهد. برای بدست آوردن تغییرات بستر از روش آب ه...
Pyrolysis is gaining more significance as a technology used to produce alternative fuels and chemicals. This study dealt with the catalytic pyrolysis of realistic waste mixture multi-layered plastic food packaging. The thermal behavior, kinetic parameters, model packaging were determined show its potential for process scale-up. In particular, we aimed evaluate effect ZSM-5 zeolite catalyst, mod...
Through isoconversional analysis of differential scanning calorimetry data, thermally induced processes glass transition and crystallization in Cux(As2Se3)100-x chalcogenide glasses (x=1, 5, 10, 15 at.%) were investigated. The characteristic values activation energy its changes during the calculated using advanced method developed by S. Vyazovkin as well forms Kissinger Moynihan relations. resu...
in this research we have studied the effect of some transition-metals (cu, ag and au) substitutions on two-electron reduction potential of flavins by application of dft method. all geometries have been optimized at blyp level of theory and “6-31+g** + lanl2dz” mixed basis set. the frequency job at the same method and basis sets has been performed to obtain gibbs free energy of compounds. it h...
The incorporation of an organic group into sol-gel-derived silica causes significant changes in the structure and properties of these materials. Therefore, the thermal treatment of organosilica materials may require a different approach. In the present paper, kinetic parameters (activation energy, pre-exponential constant, and reaction models) have been determined from mass loss data for the de...
An efficient design of in situ combustion depends on accurate kinetic modeling of the crude oil oxidation. The kinetic triplet of the oxidation reactions of a heavy oil sample was investigated. Once the kinetic triplet is known, the kinetic equation would be deconvolved. The crude oil sample was obtained from Kuh-E-Mond reservoir, located in the southwest of Iran. The samples were analyzed usin...
Separating cathode material and Al foil from spent lithium-ion batteries (LIBs) is a critical step for LIBs recycling. As compared to chemical dissolving decomposition, the pyrolysis pretreatment an alternative simple method. In this work, kinetics of were comparatively studied using various isoconversional methods, including Flynn-Wall-Ozawa (FWO), Friedman, Kissinger-Akahira-Sunose, Starink, ...
the purpose of this study was to examine the status of supervision on departments’ heads at ferdowsi university of mashhad (fum) and realize some applied themes to provide a fit model for supervising departments’ heads in fum. the method was case study under a research category aimed for applied one. using purposive sampling, interviews were conducted with top fum managers, head departments, an...
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