BACKGROUND Although most reported biogenic Mn oxides are hexagonal birnessites, other types of biogenic Mn oxides also commonly occur in the environment. However, sorption characteristics and underlying mechanisms of the adsorption of heavy-metal ions on these biogenic Mn oxides are still rarely addressed. In this study, the sorption mechanisms of Cu(II) on a low valence biogenic Mn oxide, poor...

Mechanosynthesis of La1-xSrxMnO3 (x = 0, 0.25, 0.5, 0.75 and 1) was carried out at room temperature from stoichiometric mixtures of La2O3, Mn2O3 and SrO, obtaining monophasic powders with the perovskite structure. Physical properties of these materials and their chemical compatibility with the electrolyte yttria stabilized zirconia (YSZ), which depend strongly on the La/Sr ratio, were evaluated...

A complete package [ensemble, complex] of physical and chemical investigations was conducted: x-ray phase analysis, differential thermal analysis waste generated in the production vanadium. It established that these wastes, which contain 17.39% Mn2O3 their composition, are a promising raw material for wall ceramics with volumetric-staiing. The effect heat treatment at 200, 500, 600, 700°C on co...

Using a combination of high-angle annular dark-field scanning transmission electron microscopy and atomically resolved electron energy-loss spectroscopy in an aberration-corrected transmission electron microscope we demonstrate the possibility of 2D atom by atom valence mapping in the mixed valence compound Mn3O4. The Mn L(2,3) energy-loss near-edge structures from Mn2+ and Mn3+ cation sites ar...

The high voltage spinel LiNi0.5Mn1.5O4 is a promising cathode material in next generation of lithium ion batteries. In this study, LiNi0.5Mn1.5O4 with various particle microstructures are prepared by controlling the microstructures of precursors. LiNi0.5Mn1.5O4 spinel samples with solid, hollow and hierarchical microstructures are prepared with solid MnCO3, hollow MnO2 and hierarchical Mn2O3 as...

The 0 60 "buckyball" I a prominent member of the recently discovered family of fullerene molecules, is an unusual system with exciting properties. This contribution summarizes the present state of theoretical understanding of the equilibrium structure of carbon clusters, in particular the fullerenes, the optical properties of individual fullerene molecules, superconductivity in the alkali-inter...