The exact structure of the active site of intermediate Q, the methane-oxidizing species of soluble methane monooxygenase (sMMO), and the reaction mechanism of Q with methane molecule are still not fully clear. To gain further insights into the structure and reaction mechanism, five diiron models of Q that differ in shape, oxidation state, spin state, and coordination number of the two iron cent...

Convergent lines of molecular, carbon-isotopic, and phylogenetic evidence have previously indicated (Hinrichs, K.U., Hayes, J.M., Sylva, S.P., Brewer, P.G., DeLong, E.F., 1999. Methane-consuming archaebacteria in marine sediments. Nature 398, 802±805.) that archaea are involved in the anaerobic oxidation of methane in sediments from the Eel River Basin, o€shore northern California. Now, further...

zinc (ⅱ) tricarboxylate (zn-btc) with metal-organic framework (mof) has been synthesized for the first time under solvothermal conditions and has been tested as an adsorbent for methane and carbon dioxide at standard temperature and pressure. the adsorbent was characterized by means of x-ray diffraction(xrd), brunauer-emmet-teller (bet), fourier transform infrared (ft-ir) and scanning electron ...

in order to evaluate chemical mutation on cultivar mahali tarrom’ in salt stress, seeds of rice cultivar ‘mahali tarrom’ were treated with two chemical mutagens, ethyl methane sulfonate (14 mm) and sodium azide (two mm). in second generation, appropriate plants for economically important traits have been selected. seeding of selected plants were tested under salt stress in third generation usin...

Background: Mammalian herbivores produce methane during digestion. Questions: Do ruminants (such as bovids) produce more methane during digestion than do equids (non-ruminants)? What are the effects of allometric scaling of methane production when different species feed on similar diets? Methods: From the literature, we collected a set of data on methane production (litres ·day) of ruminants (b...

It is assumed that small herbivores produce negligible amounts of methane, but it is unclear whether this is a physiological peculiarity or simply a scaling effect. A respiratory chamber experiment was conducted with six rabbits (Oryctolagus cuniculus, 1.57±0.31 kg body mass) and six guinea pigs (Cavia porcellus, 0.79±0.07 kg) offered grass hay ad libitum. Daily dry matter (DM) intake and DM di...

We present a non-equilibrium molecular dynamics simulation of 125 methane molecules using a variant of the isokinetic “sllod” algorithm. The shear viscosity, pressure and internal energy of methane in a dense, supercritical fluid state (temperature 285.7 K and mass density 0.288 g/cm3) are calculated and the viscosity compared with experiment, with excellent agreement: the predicted shear visco...

In the absence of fractures, methane bubbles in deep-water sediments can be immovably trapped within a porous matrix by surface tension. The dominant mechanism of transfer of gas mass therefore becomes the diffusion of gas molecules through porewater. The accurate description of this process requires non-Fickian diffusion to be accounted for, including both thermal diffusion and gravitational a...

the aim of the present paper was to assess the maximum biochemical methane potential (bmp) of municipal solid waste. a fresh stock of the biodegradable fraction of municipal solid waste was composed based on the typical composition of biodegradable waste disposed at the landfill. bmp tests were performed under controlled conditions. the cumulative methane generation profile was corrected for me...