BACKGROUND Monomers of methacrylates used in restorative dentistry have been recently reported to induce DNA double-strand breaks (DSBs) in human gingival fibroblasts (HGFs) in vitro. Because such monomers may penetrate the pulp and oral cavity due to the incompleteness of polymerization and polymer degradation, they may induce a similar effect in vivo. DSBs are the most serious type of DNA dam...

The aim of this study was to analyse leachable monomers, additives, and degradation products from polymer-based orthodontic base-plate materials. One heat-cured resin (Orthocryl), one light-cured (Triad VLC), and three thermoplastic materials (Biocryl C, Essix A+, and Essix Embrace) were investigated. Elution was performed in water at 37°C for 10 days. The extract medium was changed and analyse...

By combining thermostimulated current and dynamic dielectric spectroscopies, the dielectric properties characteristic of the molecular mobility can be described over a very broad frequency range. The study of dielectric relaxations of phosphorus-containing dendrimers in the sub-glass transition region, and of poly(n-alkyl methacrylates) at and above the glass transition region allows us to gain...

Organic superbases reacted with alkyl iodides (R–I) to reversibly generate the corresponding alkyl radicals (R). Via this reaction, organic superbases were utilized as new and highly efficient organic catalysts in living radical polymerization. The superbase catalysts included guanidines, aminophosphines and phosphazenes. Low-polydispersity polymers (Mw/Mn = 1.1–1.4) were obtained up to high co...

The aza-Michael addition of 1,2,3,6-tetrahydrophthalimide with symmetrical fumaric esters has been performed efficiently in a solvent-free system at 100 °C and using 1,4-diazabicyclo[2.2.2]octane (DABCO) as a base in the presence of tetrabutylammonium bromide (TBAB). The products were obtained in good to high yields within 2.5-7.0 h. This reaction worked well on linear alkyl fumarates and was n...

A 57-year-old female presented with facial oedema, cheilitis and stomatitis that started after three overnight applications of the ‘Evolution’TM home tooth-whitening kit. Her symptoms slowly resolved without treatment 3 days after she stopped using the product. The whitening kit includes an individualized plastic dental mould, which is prepared by the dentist, and a whitening gel, which contain...