Tailoring the polymer-metal interface is crucial for advanced material design. Vacuum deposition methods for metal layer coating are widely used in industry and research. They allow for installing a variety of nanostructures, often making use of the selective interaction of the metal atoms with the underlying polymer thin film. The polymer thin film may eventually be nanostructured, too, in ord...

We present a detailed theoretical analysis of the noble-gas nuclear spin relaxation due to the anisotropic magnetic-dipole hyperfine interaction between the noble-gas nucleus and alkali-metal valence electron vis à vis the already well-understood (spin-conserving) isotropic magnetic-dipole hyperfine interaction in alkali-metal–noble-gas systems. We find that, for all pairs in which the noblegas...

Co2VO4 with Co tetrahedrons and octahedrons of transition metal oxides has achieved progress in electrocatalysts batteries. However, high metal-metal interactions make it challenging to maintain reactivity as well increase the conductivity stability supercapacitors. In this work, spinel-structured CoZn0.5V1.5O4 a specific surface area was synthesized through an ion-exchange process from metal-o...

The Shockley-Queisser analysis provides a theoretical limit for the maximum energy conversion efficiency of single junction photovoltaic cells. But besides the semiconductor bandgap no other semiconductor properties are considered in the analysis. Here, we show that the maximum conversion efficiency is limited further by the excited state entropy of the semiconductors. The entropy loss can be e...

The sorption behaviour of divalent cations M2+ (Cu, Pb and zn) and trivalent cations M3+ (Fe, Al) with humic acid isolated from oxidized coal (Hazro,se Anatolia,Turkey) was followed in aqueous solution. Coal humic acid and metal ion interaction was investigated with special emphasis on the effects of pH, metal ion concentration and humic acid concentration. it has been found that the interactio...