msu-s mesoporous catalyst with [sio2]/[al2o3] ratio of 55 was synthesized using tetrapropylammonium hydroxide (tpaoh) as a structure directing agent and hexadecyltrimethylammonium bromide (ctab) as a surfactant. the catalytic activity of the calcined sample was evaluated for the dehydration of methanol to dimethyl ether (dme) in a vertical fixed bed microreactor at a weight hurly space velocity...

A profile of microRNA (miRNA) and mRNA expression patterns across the NCI-60 cell-line screen was analyzed to identify expression signatures that correlate with sensitivity to FdUMP[10], fluorouracil (5FU), floxuridine (FdU), topotecan, and irinotecan. Genome-wide profile analyses revealed FdUMP[10] resembles FdU most closely and shows dissimilarities with 5FU. FdUMP[10] had the largest dynamic...

Mesoporous nanostructures represent a unique class of photocatalysts with many applications, including splitting of water, degradation of organic contaminants, and reduction of carbon dioxide. In this work, we report a general Lewis acid catalytic template route for the high-yield producing single- and multi-component large-scale three-dimensional (3D) mesoporous metal oxide networks. The large...

Coesite nanocrystals have been synthesized from periodic mesoporous organosilica (PMO) with (CH(2))(2) bridges heated at 300 °C for 150 min and 12 GPa. The crystals are not sintered, single crystalline, and have diameters of ca. 100-300 nm. Below 300 °C, an amorphous non-porous organosilica glass was obtained. Heating above 300 °C at 12 GPa results in the rapid crystal growth and micron size co...

Mesoporous Co3O4 nanoplates were successfully prepared by the conversion of hexagonal β-Co(OH)2 nanoplates. TEM, HRTEM and N2 sorption analysis confirmed the facet crystal structure and inner mesoporous architecture. When applied as anode materials for lithium storage in lithium ion batteries, mesoporous Co3O4 nanocrystals delivered a high specific capacity. At 10 C current rate, as-prepared me...

in this research, mesoporous silica was applied as the host of corrosion inhibitor (molybdate). the loaded mesoporous silica was dispersed in an epoxy matrix. the composite was then coated on the mild steel plate. results showed that the corrosion resistance of the scratched epoxy/mesoporous silica loaded by molybdate was better than the one without molybdate or neat epoxy. on the other hand, e...

We have prepared multifunctional magnetic mesoporous Fe-CaSiO3 materials using triblock copolymer (P123) as a structure-directing agent. The effects of Fe substitution on the mesoporous structure, in vitro bioactivity, magnetic heating ability and drug delivery property of mesoporous CaSiO3 materials were investigated. Mesoporous Fe-CaSiO3 materials had similar mesoporous channels (5-6 nm) with...

Mesoporous ZnS-NiS composites are prepared via ion- exchange reactions using ZnS as the precursor. The prepared mesoporous ZnS-NiS composite materials have large surface areas (137.9 m(2) g(-1)) compared with the ZnS precursor. More importantly, the application of these mesoporous ZnS-NiS composites as nonenzymatic glucose sensors was successfully explored. Electrochemical sensors based on meso...

In this paper, we report a UV/ozone-assisted method for low temperature preparation of mesoporous TiO2 with controlled crystalline phase. The results showed that the crystallization of mesoporous TiO2 can occur at temperatures as low as 100 C under UV/ozone irradiation. Highly crystalline mesoporous anatase TiO2 was obtained after UV/ozone treatment at 200 C. The phase transformation from anata...