The isotypic title one-dimensional coordination polymers, [CdCl2(C18H14N4O4)] n , (I), and [HgCl2(C18H14N4O4)] n , (II), are, respectively, the cadmium(II) and mercury(II) complexes of the dimethyl ester of 5,6-bis-(pyridin-2-yl)pyrazine-2,3-di-carb-oxy-lic acid. In both compounds, the metal ions are located on a twofold rotation axis and a second such axis bis-ects the Car-Car bonds of the pyr...

A simple and derivative spectrophotometric method has been developed for the determination of mercury (II) using Diacetylmonoxime benzoylhydrazone (DMBH). Mercury (II) forms an orange coloured water soluble complex with the reagent in basic medium (pH 10.5).The molar absorptivity and Sandell’s sensitivity of coloured species are 2.01 x 10 L.mol cm and 0.0099 μg/cm respectively. Beer’s law is ob...

All mercurial compounds are toxic and they affect many organ systems both during pre-natal and post-natal development and in adulthood. Mercury compounds are neurotoxic. Some are immunologically active. The main toxicity stems from the binding of mercury to sulfhydryl groups of enzymes and other proteins, thereby disrupting their structure and function. This interferes with basic cellular proce...

The relationship of merA gene expression (specifying the enzyme mercuric reductase) to mercury volatilization in aquatic microbial communities was investigated with samples collected at a mercury-contaminated freshwater pond, Reality Lake, in Oak Ridge, Tenn. Levels of merA mRNA transcripts and the rate of inorganic mercury [Hg(II)] volatilization were related to the concentration of mercury in...

This chapter first presents available measurement data for mercury in environmental media and biota. This is followed by a discussion of efforts to collect measurement data from remote locations and near anthropogenic sources of concern. Note that this chapter does include measured mercury concentrations in wildlife that function as vectors to humans but does not include measured concentrations...

OBJECTIVES To determine contact allergies in patients with oral lichen planus and to monitor the effect of partial or complete replacement of amalgam fillings following a positive patch test reaction to ammoniated mercury, metallic mercury, or amalgam. DESIGN In group A (20 patients), the oral lesions were confined to areas in close contact with amalgam fillings. In group B (20 patients), the...