Femtosecond time-resolved infrared spectroscopy was employed to study intramolecular charge transfer in triphenylmethane dyes, including malachite green (MG), malachite green carbinol base (MGCB), and leucomalachite green (LMG). A local excited state (LE) and a twisted intramolecular charge-transfer (TICT) state have been observed directly in MG. Furthermore, solvent-controlled TICT measurement...

A concept is presented, which helps to rationalize the success of the industrially applied preparation route for Cu/ZnO/(Al2O3) catalysts. Many studies can be found in the open literature, which describe the critical dependency of the final catalyst’s properties on precursor chemistry. In line with previous reports, this concept identifies zincian malachite as the relevant precursor phase and i...

In this study, the sorption of Malachite green (MG) on Hydrilla verticillata biomass, a submerged aquatic plant, was investigated in a batch system. The effects of operating parameters such as temperature, adsorbent dosage, contact time, adsorbent size, and agitation speed on the sorption of Malachite green were analyzed using response surface methodology (RSM). The proposed quadratic model for...

Two advances in the development of a one-pot method to prepare silver nanoparticles (AgNPs) using the Tollens' reagent are described. First, a template-directed process of AgNP synthesis using resorcinol triazole ligands bearing two pendent galactose sugars is shown. Second, the conversion of these AgNPs into SERS nanotags is demonstrated using malachite green isothiocyanate as the Raman report...

Zincian georgeite, an amorphous copper-zinc hydroxycarbonate, has been prepared by co-precipitation using acetate salts and ammonium carbonate. Incorporation of zinc into the georgeite phase and mild ageing conditions inhibits crystallisation into zincian malachite or aurichalcite. This zincian georgeite precursor was used to prepare a Cu/ZnO catalyst, which exhibits a superior performance to a...

Application of activated carbon developed from rice husk, an agricultural waste product has been investigated for the removal of malachite green from aqueous solutions and wastewaters. Batch adsorption experiments were carried out for the removal of malachite green from aqueous solutions onto rice husk activated carbon. Effect of important parameters namely initial concentration of dye and cont...

Field experiments in copper smelting were carried out order to test assumptions about the production processes employed at Vilabouly Complex (VC), an Iron Age extraction and site central Laos. VC is one of only three primary sites known Southeast Asia appears be a major mining locale. Analytical results on assemblage (ores, crucibles, slag fragments alloy objects), along with geological informa...

An accurate, rapid, and inexpensive method was developed for detecting and enumerating bacteria adherent to Foley urinary catheters based on malachite green staining of acridine orange-prestained specimens. This method has proven to be quick and reliable and will find application in quantitative studies of biomaterial-related sepsis.

A nano-hybrid based on polystyrene derivatives and magnetite was introduced as a new sorbent for pretreatment and determine the trace amount of malachite green from aqueous solution by spectrophotometry after preconcentration by solid phase extraction (SPE). UV–Vis spectrophotometer was used for determination of MG concentration after desorption of the dye by hydrochloric acid solution in the s...

Adsorption of malachite green (MG) from aqueous solution onto treated ginger waste (TGW) was investigated by batch and column methods. The effect of various factors such as initial dye concentration, contact time, pH and temperature were studied. The maximum adsorption of MG was observed at pH 9. Langmuir and Freundlich isotherms were employed to describe the MG adsorption equilibrium. The mono...