The complexation behavior of pillar[6]arene hosts towards a carbonium ion, tropylium tetrafluoroborate (T·BF4), and the formation of novel charge-transfer (CT) inclusion complexes are described. In contrast, smaller pillar[5]arenes and larger pillar[7]arenes cannot form such complexes due to the unsuitable cavity dimensions.

A pillar[4]arene[1]quinone and a difunctionalized pillar[5]arene have been synthesized by partial oxidation.

Until quite recently, the Chinese pension system was an enterprise-based, pay-as-you-go, defined benefit scheme. In 1995, the decision was made to shift to a multi-pillar scheme that included a second funded defined contribution pillar. The transition is proving difficult. This article outlines an alternative second pillar that may make more sense for China, a pay-as-you-go notional defined con...

Layers of end-grafted weak polyelectrolytes in poor solvent self-organize into a rich variety of structures (such as micelles, micelles coexisting with nonaggregated chains, stripes and layers with solvent-filled holes) due to the subtle competition among hydrophobic, electrostatic and steric interactions and the chemical acid-based equilibria of the weak polyelectrolyte. In this work, a molecu...

To construct a bridge as a crossing building on a very wide river it might not used one span only, therefor, in middle of the river it is needed pillar as support. The existing of the pillars will change velocity distribution, surface water and topography of sediment, especially when the pillar is located on the bend of the river where the very large hydraulic can be hepened. Therefore, this st...

This nationwide prospective study was designed to determine prognostic factors and evaluate the outcome of different treatments of Perthes' disease. A total of 28 hospitals in Norway were instructed to report all new cases of Perthes' disease over a period of five years and 425 patients were reported and followed for five years. Of these, 368 with unilateral disease were included in the present...

We have synthesized a pillar[6]arene in high yield and a co-pillar[6]arene using chlorocyclohexane as a solvent.

Gap junctional intercellular communication (GJIC) plays a major role in cochlear function. Recent evidence suggests that connexin 26 (Cx26) and Cx30 are the major constituent proteins of cochlear gap junction channels, possibly in a unique heteromeric configuration. We investigated the functional and structural properties of native cochlear gap junctions in rats, from birth to the onset of hear...

The australopithecine anterior pillars defined by Rak (The Australopithecine Face, New York: Academic Press, 1983) were re-examined in the fossil hominids of southern Africa. The structure and extent of this buttressing pillar was found to be variable among Australopithecus africanus and A. robustus specimens. A reduced anterior pillar was observed in Homo habilis, and a morphological equivalen...

Room-and-pillar mining with pillar recovery has historically been associated with more than 25% of all ground fall fatalities in underground coal mines in the United States. The risk of ground falls during pillar recovery increases in multiple-seam mining conditions. The hazards associated with pillar recovery in multiple-seam mining include roof cutters, roof falls, rib rolls, coal outbursts, ...