In the core of Chemical Engineering is the reactor design that includes most of all scientific disciplines. The reactor, in general, are treated ideally: mixed and plug-flow patterns. Unfortunately, it is observed in the real world a very different behavior from that expected. Thus, to characterize nonideal reactors is used, among others, residence time distribution function E(t), mean residenc...

Dehydration of ethanol via adsorption on 3Å molecular sieves has recently been increasing in application in industry as an alternative to the conventional separation techniques for breaking the ethanol-water azeotrope. Over the past 20 years, Pressure-Vacuum Swing Adsorption (PSA) processes have gained increasing commercial acceptance as an energy-efficient separation technique. A general purpo...

Heat and mass transfer problem in a fixed-bed tubular reactor is one of the major concerns in the chemical engineering. The two dimensional axial plug flow model was used for a water gas shift reactor to compare heat conduction or mass diffusion with convective effect. In the case of fast fluid flow in highly permeable catalyst-bed, convective heat transfer was dominant compared to heat conduct...

Dispersion and spreading of concentration signals in gas/liquid microreactors is studied with methods of computational fluid dynamics (CFD). It is shown that conventional reactor designs exhibit a broad residence-time distribution due to convective signal dispersion. This result is supported by experiments monitoring the transport of a liquid plug introduced into the microreactor by a microdisp...

A multicomponent one-dimensional dynamic mathematical model for the reacting slurry systems with a change in gas flow rate due to the chemical reaction is developed. A change in gas flow rate caused by the chemical reaction is modeled using the overall gas mass balance. Thus, all relevant chemical species are included in the model. Linear first-order reaction kinetics is considered. The gas pha...

The non-isothermal continuous stirred tank reactor (CSTR) is a classical yet complex case study of nonlinear dynamical systems. Power-shaping control is a recent approach for the control of nonlinear systems based on the physics of the dynamical system and it rests on the formulation of the dynamics in the Brayton-Moser form. The Brayton-Moser formulation of the non-isothermal continuous stirre...

In this paper, we develop plug flow reactor models that simultaneously investigate how reaction and absorption, morphological differences, and temperature influence nutrient acquisition rates in simple, tubular animal guts. We present analytical solutions to the resulting reaction-advection equations that model these processes, and we obtain formulas giving the throughflow speed that maximizes ...

The coupling of reactions in catalytic membrane reactors provides novel reactor configurations that allow shifting the thermodynamic equilibrium and yields of thermodynamically limited reactions and enhancing significantly the rate of production. An interesting pair to couple is the dehydrogenation of ethylbenzene to styrene and the hydrogenation of nitrobenzene to aniline. Hydrogen produced in...

An experimental and kinetic modeling study on the Ni-catalyzed conversion of methane under oxidative and reforming conditions is presented. The numerical model is based on a surface reaction mechanism consisting of 52 elementary-step like reactions with 14 surface and six gas-phase species. Reactions for the conversion of methane with oxygen, steam, and CO2 as well as methanation, water-gas shi...