Alkyl-chain ferrocene cationic surfactants (ACFcCS) can form ion-pair complexes with anions, and are then adsorbed at hydrophobic electrode surfaces or extracted to organic layers. The amount of adsorbed ACFcCS-anion complex is dependent on the anion concentration in a solution, and the anion concentration can be determined from the current intensity of the oxidation wave of the ferrocene part ...

Ion pair dispersive liquid- liquid microextraction (IP-DLLME) method combined with flame atomic absorption spectrometry was proposed for the determination of trace amounts of copper(II). By using pyrocatechol violet as chelating agent and cetyltrimethyl ammonium bromide as an ion pairing agent, the trace amount of copper(II) was extracted in chloroform. The factors influencing the formation cop...

We have prepared and characterized a few Mn (III) complexes by using a few bidentate and tridentate ligands. Spectra of the manganese (Abstract We have prepared and characterized a few Mn (III) complexes by using a few bidentate and tridentate ligands. Spectra of the manganese (III) ion in a variety of molecular environments are reported . On the basis of solution spectra, some of these co...

n-propylsalicylidene based on silica as ion exchanger (ie) was used for the separation by complexation of mn2+, co2+, ni2+, cu2+, hg2+, cr3+, fe3+, and uo22+ from their parent solutions. ie and its metal complexes are characterized by elemental analysis, electronic and infrared spectra, in addition to thermal analysis in atmospheric pressure. the mode of chelation and the proposed geometric str...

Six alkali metal tris(HMDS) magnesiate complexes (HMDS, 1,1,1,3,3,3,-hexamethyldisilazide) containing chiral diamine ligands have been prepared and characterised in both the solid- and solution-state. Four of the complexes have a solvent-separated ion pair composition of the form [{M·(chiral diamine)(2)}(+){Mg(HMDS)(3)}(-)] [M = Li for 1 and 3, Na for 2 and 4; chiral diamine = (-)-sparteine for...

Among the polar interactions occurring in pancreatic lipase/colipase binding, only one ion pair involving lysine 400 on lipase and glutamic acid 45 on colipase has been described. These residues are strictly conserved among species, suggesting that the ion pair is likely to play an important role. Therefore, in order to prevent this interaction, mutations intended to neutralize or inverse the c...

Using the evaporating method, the solubility of potassium Nitrate was determined in various mixtures containing Water and Ethanol at 25°C. The results show that the solubility of KNo3 decreases with increasing the mass percent of Ethanol in the mixtures. This trend is along with decreasing the dielectric constant of Water+Ethanol mixtures. Moreover, it can be concluded that the totqal solubilit...

lead, copper, cobalt, nickel, iron and zinc ions form monocitrate complexes (negative charge) in citrate solution which is absorbed on the citrate form of anion-exchange resins (citrate as counter ion) y exchange of citrate ion with citrate complexes. these are subsequently recovered from the resin by 0.5m ammonium citrate eluent at ph 2.0. under optimized conditions, quantitative recovery was ...

Using the mixed solvents, (water +ethanol + propanol), the solubility of CdF2 was determined byevaporating method at 25° C. The results showed that the sollbility, s, of CdF2 decreases bydecreasing the dielectric constant of the mixed solvent .Once the solubility of CdF2 was determined,the concentration solubility product, Ksp(c)=4s3, was calculated .Furthermore ,by estimating the meanactivity ...

Ab initio MP2/aug’-cc-pVTZ calculations have been performed to determine selected stretching frequencies and chemical shieldings for ternary complexes N-base:PH2F:BeX2 the corresponding binary complexes, with NH3, H2C=NH, HCN as nitrogen bases H, F, Cl substituents X. Be-F P-F depend on distances, respectively, while P F N-P respectively. The graph of versus distance bears a remarkable resembla...