The complex [Rh(I(t)Bu)(2)HCl] has been shown to be an active catalyst in the hydrosilylation of carbonyl and imine complexes. This reactivity, combined with the previously reported H/D exchange catalyzed by these complexes allows for a one pot, two step reaction using a single catalyst for both H/D exchange and hydrosilylation. Using triethylsilane, [Rh(I(t)Bu)(2)Cl] catalyst, and D(2) gas, de...

A dinuclear N-heterocyclic carbene (NHC) copper complex efficiently catalyzes azide-alkyne cycloaddition (CuAAC) "click" reactions. The ancillary ligand comprises two 4,5-dimethyl-1,3-thiazol-2-ylidene units and an ethylene linker. The three-step preparation of the complex from commercially available starting compounds is more straightforward and cost-efficient than that of the previously descr...

Ammonium ions wastewater pollution has become one of the most serious environmental problems today. The treatment of ammonium ions is a special concern due to their recalcitrance and persistence in the environment. In recent years, various methods for ammonium ion removal from wastewater have been extensively studied. This paper reviews the current methods that have been used to treat ammonium ...

a new category of hybrid organic-inorganic zirconium phosphonate, zr[(o3pch2)2nc6h4co2h].2h2o was synthesized and the applicability of the prepared sorbent as an ion-exchanger for removal of ni2+, cu2+ and zn2+ from aqueous solutions was evaluated. the characterization of the synthesis product was done using tg-dtg, sem, xrd, ft-ir techniques. study of the sorption isotherms and its kinetic par...

securigera securidaca (l.) degen & dorfl grows in different parts of iran. the seeds of the species are used in iranian folk medicine as an anti-diabetic agent. many studies have established hypoglycemic effects of amino acids and in the present investigation, amino acids of securigera securidaca seeds have been evaluated. the ground seeds were extracted using petroleum ether, hot ethanol a...

introduction: polyclonal antibodies are required to be affinity purified. improved purification methods of polyclonal antibody provide an opportunity to pick the most purified immunoglobulins as a primary or secondary antibody in immunoassays that are included in many vaccine studies. two common techniques for purifying proteins is salt precipitation and chromatography purification. our work fo...

objective: bleaching of the teeth is considered as a safe, effective, and conservative procedure to treat discolored teeth. the aim of the present study was to compare the amount of mercury and silver released from amalgam after applying two brands of carbamide peroxide 16% bleaching gel. materials and methods: for this experimental study, 384 amalgam tablets were prepared. the samples were kep...

Alumina is an inorganic material, which is widely used in ceramics, catalysts, catalyst supports, ion exchange and other fields. The micromorphology of alumina determines its application in high tech and value-added industry and its development prospects. This paper gives an overview of the liquid phase synthetic method of alumina preparation, combined with the mechanism of its action. The pres...

ammonium ions wastewater pollution has become one of the most serious environmental problems today. the treatment of ammonium ions is a special concern due to their recalcitrance and persistence in the environment. in recent years, various methods for ammonium ion removal from wastewater have been extensively studied. this paper reviews the current methods that have been used to treat ammonium ...