The microwave spectra of (CH3)3GeBr and its isotopologues (CH3)3GeBr and (CH3)3GeBr have been studied in the frequency range from 2.4-20 GHz revealing the complex internal dynamics of this organometallic molecule with three internal rotors. The assignment of the complex spectrum has been facilitated by permutation-inversion theory the appropriate molecular symmetry group is G162. The V3 barrier...

We report an experimental study of the adhesion properties of polydopamine thin films and their bonding behavior on polymer, glass and metal surfaces. Dopamine is able to adsorb onto all surfaces and self-polymerize into a thin hydrophilic film. Dynamic contact angle measurements revealed a large contact angle hysteresis between advancing and receding angles and a possible hydration layer when ...

Configurational contributions of hydrogen bonds to thermodynamic properties of water (internal energy, entropy, and heat capacity) are calculated on the basis of statistical distributions of frequencies of the OH vibrations of liquid water, calculated earlier from the experimental Raman spectra in frameworks of the fluctuation theory of hydrogen bonding. Distributions of the energy of hydrogen ...

C-type inactivation of potassium channels fine-tunes the electrical signaling in excitable cells through an internal timing mechanism that is mediated by a hydrogen bond network in the channels' selectively filter. Previously, we used nonsense suppression to highlight the role of the conserved Trp434-Asp447 indole hydrogen bond in Shaker potassium channels with a non-hydrogen bonding homologue ...

One of the most common methods to measure soil mechanical properties (namely cohesion and internal friction angle) is direct shear box test. In this paper the development of a three-dimensional (3D) discrete element soil model for simulation of a cohesive soil’s direct shear test is presented. The aim was to calibrate the properties of the Hertz-Mindlin with bonding contact model available in E...

Porphyrinic compounds comprise a diverse group of materials which have in common the presence of one or more cyclic tetrapyrroles known as porphyrins in their molecular structures. The resulting aromaticity gives rise to the semiconducting properties that make these compounds of interest for a broad range of applications, including artificial photosynthesis, catalysis, molecular electronics, se...

The nanostructures of self-assembling biomaterials have been previously designed to tune the release of growth factors in order to optimize biological repair and regeneration. We report here on the discovery that weakly cohesive peptide nanostructures in terms of intermolecular hydrogen bonding, when combined with low concentrations of osteogenic growth factor, enhance both BMP-2 and Wnt mediat...

The electronic structure of nanolaminate Ti2AlC and Ti2AlN thin films, so-called MAX-phases, were investigated by soft X-ray emission spectroscopy. These nanolaminated carbide and nitride compounds represent a class of layered materials with a combination of properties from both metals and ceramics. The bulk-sensitive soft X-ray emission technique is particularly useful for detecting detailed e...