an efficient and green method for the synthesis of pyrano[3,2-c]chromene or pyrano[4,3-b]pyrone derivatives is described by using a three-component condensation process of malononitrile, aldehyde, and 4-hydroxycoumarine or 4-hydroxypyrone in [bmim]bf4-licl as an ionic liquid.

one-pot preparation of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles has been conducted in the presence of poly(4-vinylpyridinium butane sulfonic acid) hydrogen sulfate, p(4vpbsa)hso4, as an efficient dual acidic catalyst under solvent-free conditions. reusability of the catalyst, easy work-up procedure, eco-friendly reaction conditions, short reaction times and high yields of th...

in the present investigation, a novel adsorbent, ionic liquid modified magnetic nanoparticles (il-fe3o4), was successfully synthesized and characterized by ft-ir spectroscopy, thermogravimetric analysis (tga), xrd analysis, scanning electron microscopy (sem) and theory of brunauer, emmett, and teller (bet) for removal of reactive orange 122 (ro-122) from aqueous solutions. the effects of variou...

Liquid crystal-based materials, in which liquid crystal molecules are confined and ordered compartments, dynamic materials yielding a variety of optical textures that can be tuned as response to physical chemical stimuli. While nematic smectic-based gel have been reported sensors report volatile organic compounds (VOCs), chiral systems less explored despite having the potential yield extremely ...

a series of 2-amino pyridine-3-carbinitrile derivatives incorporated coumarin moiety has developed via multicomponent condensation of 3-acetyl-2h-chromen-2-one, arylaldehydes, malononitrile and ammonium acetate utilizing brønsted acidic ionic liquid, (4-sulfobutyl)tris(4-sulfophenyl)phosphonium hydrogen sulfate as catalyst under solvent-free conditions. good yields, short reaction times, straig...

a simple and mild procedure for the conversion of anilines into aryl isocyanates is described using the 3-hydroxypropylammonium acetate (hpaa) ionic liquid as a novel and efficient media has been explored in the synthesis of aryl isocyanates from the reaction of substituted urea with sodium nitrite in a water immiscible solvent. this ionic liquid can be easily recovered and reused for many time...

the brønsted acidic ionic liquid ([bmim]hso4) catalyzed three-component synthesis of 2h-indazolo[2,1-b]phthalazine-trione derivatives at room temperature. the integrity of the ionic liquid remains reasonably unchanged when it is separated from the reaction mixture by water extraction, as it can be recycled several times without any loss of activity in each of the title syntheses. the products a...

urease was immobilized on platinum electrode both by chemical binding and electropolymerization.the conductometric urea biosensor thus prepared showed a detection limit of 4.9×10-5 m and linear dynamic range from 4.9×10-5 to 5.8×10-3 m for urea concentration when the enzyme is covalently immobilized on pt electrodes. conductometric transducers respond to the changes in ionic strength thereby le...

This work reports a sensitive amperometric biosensor for organophosphate pesticides (OPs) fabricated by modifying a glassy carbon electrode with acetylcholinesterase (AChE) immobilized on ionic liquid-functionalized graphene (IL-G). The functionalized graphene sheets had good dispersibility and long-term stability in various solvents. The as-prepared biosensor showed high affinity to acetylthio...

The effect of immobilized dye concentration on protein complexation was observed using zonal chromatography. A monomeric protein, octopine dehydrogenase, was retained by a single interaction to a Sepharose CL-6B column containing 11.6 mM immobilized Cibacron blue F3GA. By contrast, a tetrameric protein, lactate dehydrogenase, was retained by the same column by multiple interactions. The degree ...