Introduction The presence of certain heterocyclic rings with nitrogen atoms in an organic polymer may significantly improve its thermal stability. For typical polyurethane foams, the upper temperature range of save usage is usually considered to be 90-110°C [1, 2]. This limit can be improved by applying an oligoetherol component containing a thermostable heterocyclic ring with nitrogen atoms, s...

The microwave-assisted reaction of 2-nitroimidazole with 3-bromophenacyl bromide in the presence potassium carbonate as a base and dimethylformamide solvent afforded 2-(3-bromophenyl)imidazo[2,1-b]oxazole. formation this compound was explained via domino mechanism comprising an initial N-alkylation imidazole substrate, followed by base-promoted deprotonation position adjacent to carbonyl give e...

the ir and nmr spectra were coupled with quantum chemical calculations in dft approach usingthe hybrid b3lyp exchange-correlation functional to confirm the structure of 2-methoxycarbonyl-7-methyl-1,3-thiazino[3,2-b][1,2,4]triazine-4,8-dione 2d.

In the title compound, [Fe(CH(3)CN)(3)(C(29)H(27)N(5)OP(2))](BF(4))(2)·2CH(3)CN, the Fe(II) ion is octa-hedrally coordinated by a meridionally chelating tridentate pincer-type PNP ligand derived from 2,6-diamino-4-eth-oxy-1,3,5-triazine and by three acetonitrile mol-ecules. The four Fe-N bond lengths range from 1.9142 (12) to 1.9579 (11) Å, while the Fe-P bonds are 2.2452 (4) and 2.2506 (4) Å [...

The title compound, C21H33N3O3, is a tri-substituted cyclo-hex-yloxy triazine. In the crystal, the triazine rings form (C3i-PU) Piedfort units. The inter-centroid distance of the π-π inter-action involving the triazine rings is 3.3914 (10) Å. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming ribbons propagating along [1-10]. There are also weak C-H⋯N and C-H⋯O contacts pres...

The photodegradation of Azinphos-ethyl (1) in chloroform and methanol solution has been studied. 3,4-D ihydro-3-m ethyl-4-oxobenzo[d][l,2,3]triazine (3), 3,4-dihydro-4-oxo-benzo[d][l,2,3]triazine (5), 0 ,0-d iethyl-0(3-m ethylbenzo[d][l,2 ,3]triazine-4-yl)phosphate (8), N-methylanthranilic acid (11) (in methanol: methyl ester 12), and sulfur have been isolated and charac­ terized as photoproduc...

A simple and practical method has been developed for the regioselective nitrosylation of imidazopyridines via C(sp(2))-H bond functionalization using tert-butyl nitrite under mild reaction conditions in a short time. A library of 3-nitrosoimidazopyridines with broad functionalities was synthesized in near quantitative yields. The present protocol is also applicable to imidazo[2,1-b]thiazole and...

Bu(3)SnH/1,1'-azobis(cyclohexanecarbonitrile) (ACN)-mediated five, six, and seven-membered double alkyl radical cyclizations onto imidazo[5,4-f]benzimidazole and imidazo[4,5-f]benzimidazole are described. The quinone derivatives evaluated show selective toxicity towards human cervical (HeLa) and prostate (DU145) cancer cell lines (with negligible toxicity towards a normal human cell line, GM006...

The aging of triazine amine in soil was studied during a time course of 119 d by measuring bioavailability in terms of mineralization after inoculation of the triazine amine-degrading bacterium Rhodococcus erythropolis TA57. The bioavailability was measured in four soil samples: A-, B-, and C-horizons from an agricultural soil profile and in a peat soil. The sorption of triazine amine in the so...

Triazines are an important group of herbicides, which have been used extensively or selectively both in agricultural and non-agricultural areas worldwide for more than fifty years to control broadleaf and some grassy weeds. As a consequence of their massive application, they have become and remain significant environmental pollutants, especially in aquatic ecosystems. Fish are an integral part ...