Hydrophobic interactions normally are not considered a major driving force for self-assembling in a hydrophobic environment. When macrocyclic oligocholates were placed within lipid membranes, however, the macrocycles pulled water molecules from the aqueous phase into their hydrophilic internal cavities. These water molecules had strong tendencies to aggregate in a hydrophobic environment and te...

Capsular exopolymers (EPS) of the bacterium Pseudomonas sp. NCIMB 2021 are allowed to self-assemble on hydrophilic and hydrophobic gold surfaces. Tapping mode atomic force microscopy confirms the differences in the surface topography between EPS adsorbed on both surfaces. Fourier-transform IR spectroscopy indicates that the EPS surface coverage is much greater on the hydrophobic surface. Furthe...

The underlying mechanism of UV light-induced dissociation and visible light-induced reformation of vesicles formed by an azobenzene diblock copolymer was investigated. These processes were studied in situ by monitoring changes in optical transmittance of the vesicular solution while being exposed to UV or visible light irradiation. The results indicate that the UV-induced dissociation of the ve...

PURPOSE To retrospectively evaluate the incidence of neodymium: YAG (ND:YAG) laser capsulotomies for posterior capsule opacification (PCO) seen with hydrophobic and hydrophilic acrylic intraocular lens implants 18 months after surgery. METHODS One hundred and five eyes that had phacoemulsification with a continuous curvilinear capsulorhexis and implantation of either a hydrophobic or a hydrop...

PURPOSE To investigate the ability of an open capsule device to prevent posterior capsule opacification. METHODS A total of 40 eyes of 20 New Zealand white rabbits were randomly divided into six similar groups of 6 to 7 eyes each. After crystalline lens evacuation, one control group (group A) was implanted with a hydrophilic acrylic intraocular lens and no device, and another control group (g...

We calculate the ion distributions around an interface in fluid mixtures of highly polar and less polar fluids (water and oil) for two and three ion species. We take into account the solvation and image interactions between ions and solvent. We show that hydrophilic and hydrophobic ions tend to undergo a microphase separation at an interface, giving rise to an enlarged electric double layer. We...

In the present work, Iranian natural zeolite particles (NZ) as an abundant and low-cost resource were modified by chemical covalent attachments of commercially available stearic acid (SA) with tunable hydrophobic/hydrophilic properties. The versatile, simple, and green technique of mechanogriding was performed for the hydrophobic derivatisation of NZ. The NZ and as-prepared modified particles w...