Hydrophobie Vinyl Compound, Enhancement Effect, Enzymatic Hydrolysis, Waste Paper Enzymatic hydrolysis o f waste papers in the presence of various vinyl compounds was carried out, and the addition o f the compounds such as methyl methacrylate, styrene, and vinyl acetate increased glucose yield resulting from the acceleration of the rate of the enzymatic hydrolysis. The optimum conditions existe...

Comparative study of hydrolysis of carnosine and a number of its natural derivatives by human serum and rat kidney carnosinase was carried out. The rate of carnosine hydrolysis was 3-4-fold higher then for anserine and ophidine. The rate of homocarnosine, N-acetylcarnosine and carcinine hydrolysis was negligible by either of the enzymes used. Our data show that methylation, decarboxylation or a...

Quartz crystal microgravimetry (QCM) was used to investigate the interactions between cellulase enzymes and model cellulose substrates. The substrates consisted of thin films of cellulose that were spin-coated onto polyvinylamine (PVAm) precoated quartz crystal sensors carrying conductive gold surfaces. In QCM the quartz crystals are piezoelectrically driven and the frequency and dissipation sh...

A novel beta-cyclodextrin dimer, 1,10-phenanthroline-2,9-dimethyl-bridged-bis(6-monoammonio-beta-cyclodextrin) (phenBisCD, L), was synthesized. Its zinc complex (ZnL) has been prepared, characterized, and applied as a new catalyst for diester hydrolysis. The formation constant (logK(ML)=9.56+/-0.01) of the complex and deprotonation constant (pK(a)=8.18+/-0.04) of the coordinated water molecule ...

The kinetics of chemical hydrolysis including neutral, acid- and base-catalyzed hydrolysis of 4-methylumbelliferyl caprylate (MUCAP) salmonella reagent were studied at different temperatures. The rate constants and activation parameters were determined by following the build-up of fluorescence peak of the hydrolysis product 4-methylumbelliferone (4-MU). The time scale of esterase enzyme hydroly...

Nowadays, a lot of efforts have been applied to find an appropriate catalyst for generating hydrogen from NaBH4. Hence in the current study, various nanostructures of TiO2 were employed to obtain an insight into how the different support catalysts effect on the hydrolysis rate of NaBH4. For this aim, disordered filaments (DF-NTs) and ordered free-standing TiO2 nanotubes (FS-NTs) were fabricated...

The aims of the study were to investigate the effect of poly(ε -caprolactone) (PCL) and nano- SiO2 within the thermoplastic starch (TPS) blends on the rate and extent of starch enzymatic hydrolysis using enzymes α-amylase and amyloglucosidase. The results of this study have revealed that blends with nano-SiO2 content at 6 wt% exhibited a significantly reduced rate and exte...

The change in reaction energetics of the bicarbonate-dependent ATPase reaction of Escherichia coli carbamoyl phosphate synthetase has been investigated for two site-directed mutations of the essential cysteine in the small subunit. Cysteine 269 has been proposed to facilitate the hydrolysis of glutamine by the formation of a glutamyl-thioester intermediate. The two mutant enzymes, C269S and C26...

The ability of different polyamines to catalyze hydrolysis of phosphodiester linkages in apurinic and apyrimidinic (AP) sites has been investigated in supercoiled, relaxed and denatured DNA, and also in core and chromatosome particles. The rate constants for the hydrolysis in the DNAs have been determined. In general the order of effectiveness of the polyamines were: spermine greater than sperm...