Strongly σ-donating N-heterocyclic carbenes (NHCs) have revived research interest in the catalytic chemistry of iron, and are now also starting to bring the photochemistry and photophysics of this abundant element into a new era. In this work, a heteroleptic Fe(II) complex (1) was synthesized based on sequentially furnishing the Fe(II) center with the benchmark 2,2'-bipyridine (bpy) ligand and ...

basil (ocimum basilicum l.) belongs to the lamiaceae family as a medicinal plant used in traditional medicine in iran. the purpose of this test is to evaluate the effect of nano fe-chelate under salinity levels on the plant physiology and morphology characteristics. in this experiment  investigated the effect of nano fe-chelate and salinity stress on growth parameters, photosynthetic leaves rat...

The aim of this study was to evaluate the effect of Gd-chelate on renal function, iron parameters and oxidative stress in rats with CRF and a possible protective effect of the antioxidant N-Acetylcysteine (NAC). Male Wistar rats were submitted to 5/6 nephrectomy (Nx) to induced CRF. An ionic-cyclic Gd (Gadoterate Meglumine) was administrated (1.5 mM/KgBW, intravenously) 21 days after Nx. Cleara...

A heteroleptic N(6) coordinated Ru(II) complex acts as a building block for a discrete tetranuclear mixed metal Ru(II)(2)Ag(I)(2) coordination compound; both complexes have been structurally characterised by X-ray crystallography.

The reaction of 1,3-bis(4,6-dimethylpyridyl-2-imino)isoindoline and palladium acetate in methanol selectively yields the expected acetato palladium N,N,N-chelate or a cyclometalated tetranuclear dimer depending on the stoichiometry of the reactants.

Efficient near-infrared circularly polarised luminescence (CPL) between 1400 and 1600 nm of four enantiomer pairs homo- heteroleptic complexes have been successfully measured.

The purpose of this study was to investigate the response of physicochemical properties of gerbera (Gerbera Jamesonii L.) to silica nanoparticles (Nanoparticle-SiO2) and calcium chelate (Ca-Chelate) in nutrient solutions. A factorial experiment based on completely randomized design with two factors was conducted in four replicates. The first factor the concentration of Nanoparticle-SiO2 in nutr...

The angular correlation of the 173-247 keV gamma-ray cascade after the electron-capture decay of (111)In is strongly perturbed when the 1-p-nitrophenyl-ethylenediaminetetraacetate chelate of (111)In(8+) is added to a solution containing rabbit antibody to dinitrophenyl groups. The radioactive chelate can be displaced by the addition of dinitrophenyllysine or unlabeled chelate. The average assoc...

It is suggested that under physiological conditions (> 1 mM Mg(2+)) MgATP binds to myosin to form a chelate involving the two reactive sulfhydryl sites (SH(1) and SH(2)). The stability of the chelate structure results in marked inhibition of the myosin ATPase in the presence of millimolar magnesium ion. The inhibitory effect of magnesium ion can be eliminated chemically by blocking either the S...