The oxidative coupling of sp(3) hybridized carbon atoms by photocatalysis is a valuable synthetic method as stoichiometric oxidation reagents can be avoided and dihydrogen is the only byproduct of the reaction. Cadmium sulfide, a readily available semiconductor, was used as a visible light heterogeneous photocatalyst for the oxidative coupling of benzyl alcohols and benzyl amines by irradiation...

The nano sized TiO2 and ZnO are the most active photocatalysts.  Methylene blue was used as a reference molecule for the photocatalytic degradation. The TiO2 and ZnO can totally remove methylene blue dye. The effect of various process parameters like initial concentration, contact time, dose of catalyst and pH on the extent of removal of dye by photocatalysis in presence o...

Methylthionine Chloride (MTC), commonly known as methylene blue, is a substance widely used in medical and clinical industry indicator, various diseases treatment diagnostic. When MTC discarded out of the organism, it becomes residue which ends wastewater plants not treated or removed properly because has synthetic origin, providing with stability chemical structure difficult to break. In prese...

L-Asparaginase is a chemotherapeutic drug used in the treatment of acute lymphoblastic leukaemia (ALL), a malignant disorder in children. L-Asparaginase helps in removing acrylamide found in fried and baked foods that is carcinogenic in nature. L-Asparaginase is present in plants, animals and microbes. Various microorganisms such as bacteria, yeast and fungi are generally used for the productio...

We report the latent production of free radicals from energy stored in a redox potential through a 2e(-)/1H(+) transfer process, analogous to energy harvesting in photosynthesis, using visible-light organic photoredox catalysis (photocatalysis) of methylene blue chromophore with a sacrificial sterically hindered amine reductant and an onium salt oxidant. This enables light-initiated free-radica...

In the preceding article [Pure Appl. Chem. 71, 303–320 (1999)] we examined two principal features of heterogeneous photocatalysis that demanded scrutiny: (i) description of photocatalysis and (ii) description of process efficiencies. For the latter we proposed a protocol relative photonic efficiency which could subsequently be converted to quantum yields. A difficulty in expressing a quantum yi...

Multimode polymer waveguides and fiber-to-waveguide couplers have been integrated with microfluidic channels by use of a single-mask-step procedure, which ensured self-alignment between the optics and the fluidics and allowed a fabrication and packaging time of only one day. Three fabrication procedures for obtaining hermetically sealed channels were investigated, and the spectrally resolved pr...

BACKGROUND Awareness of bovine tuberculosis (BTB) by cattle owners is of extreme importance to policy makers when considering mitigation. However, to our knowledge, little is known on cattle owners' awareness of BTB in Zambia. Similarly, such knowledge is uncommon within and outside Africa. The current study investigates the epidemiological characteristics of BTB in Zambian cattle in relation t...

The nano sized TiO2 and ZnO are the most active photocatalysts.  Methylene blue was used as a reference molecule for the photocatalytic degradation. The TiO2 and ZnO can totally remove methylene blue dye. The effect of various process parameters like initial concentration, contact time, dose of catalyst and pH on the extent of removal of dye by photocatalysis in presence o...