The direct electrochemical behaviour of peptide methionine sulfoxide reductase A (MsrA) adsorbed on glassy carbon and boron doped diamond electrodes surface, was studied over a wide pH range by cyclic and differential pulse voltammetry. MsrA oxidation mechanism occurs in three consecutive, pH dependent steps, corresponding to the oxidation of tyrosine, tryptophan and histidine amino acid residu...

Glassy carbon (GC) has been high-pressure high-temperature treated. An interesting morphology evolution from the pristine sample to the high pressure products was observed. It is found that GC can be graphitized under pressure at a temperature much lower than that at ambient condition. Furthermore the in−situ structure and electrical measurements of GC and graphitized glassy carbon (GGC) under ...

In this research, a glassy carbon electrode was coated with a thin layer of multi-walled carbon nanotubes in the presence of the surfactant and subsequently was electro-polymerized with Poly-L-arginine (P-L-Arg). The prepared electrode was used as an effective sensor for the quantitative detection of Rutin (Ru). The fabricated electrode exhibited good electrochemical performance with low electr...

This mini review describes the results regarding the voltammetric determination of micromolar, submicromolar and nanomolar concentrations of various fluoroquinolones antibacterial agents using both traditional hanging mercury drop electrode, carbon paste electrode, glassy carbon paste electrode and chemically modified electrodes. We concentrate on the interaction of quinolones with DNA in solut...

We demonstrate a method for constructing bifunctional nanostructures, which conjugate biochemical and electrocatalytic activities, on glassy carbon surfaces by decorating the carbon surfaces with both biologically active glucose oxidases and size-monodisperse Pt nanoparticles (less than 2 nm in diameter) utilizing only a single dendrimer layer.

Arrays of aligned multi-walled carbon nanotube-ionic liquid (MIL) were assembled on silicon wafers (Si-MIL). Formation of Si-MIL was confirmed by FTIR, AFM and Raman techniques. The electrochemical measurements indicated that Si-MIL showed good electrocatalysis towards oxygen reduction compared with MIL drop-cast on a glassy carbon electrode.

Electrocatalytic reduction of CO2 occurred efficiently using a glassy carbon electrode modified with a cobalt(II) chlorin complex adsorbed on multi-walled carbon nanotubes at an applied potential of -1.1 V vs. NHE to yield CO with a Faradaic efficiency of 89% with hydrogen production accounting for the remaining 11% at pH 4.6.