A copper-catalyzed domino protocol for the synthesis of 2-(1,3,4-oxadiazol-2-yl)aniline derivatives has been developed from simple and available isatins and hydrazides. This domino process integrated consecutive condensation, base-promoted ring-opening and the key copper-catalyzed decarboxylative coupling for intramolecular C-O bond formation.

Copper perchlorate hexahydrate as an efficient catalyst was used for the synthesis of polyhydroquinolines by four-component condensation reaction of aldehyde, ethyl acetoacetate, dimedone, and ammonium acetate in excellent yields and short reaction times at room temperature under ultrasound irradiation. This novel synthetic method is especially favoured because it provides a synergy between cop...

A heterotrifunctional template was developed that utilizes thiol-maleimide and click chemistries (both copper-free and copper-mediated) to effect sequential biomolecule conjugations in a one-pot process. The breadth of compatible substrates was illustrated through highly efficient conjugations of protein, peptide, sugar, lipid, fluoroalkane, biotin and fluorophore molecules. This template shoul...

Copper wires have been attracting much attention for Large Scale Integration (LSI) bonding because of their excellent mechanical and electrical properties, in addition to their low material cost. The ends of these wires are usually joined to pads or through-holes on a printed circuit board, and lead-free soldering is one of the popular bonding methods. Since the deformation resistance of solder...

Thermodynamic calculations have shown that hydrogen from atmospheric water vapors can penetrate aluminum, iron and copper, especially into their melts. Hydrogen atoms in these metals are free adsorbed states. Strong dense oxide films on the surfaces of copper significantly reduce solubility metals. Copper nanocrystals more actively adsorb atomic than aluminum nanocrystals. This is one main reas...

Copper is an essential micronutrient in humans and is required for a wide range of physiological processes, including neurotransmitter biosynthesis, oxidative metabolism, protection against reactive oxygen species, and angiogenesis. The first step in the acquisition of dietary copper is absorption from the intestinal lumen. The major human high-affinity copper uptake protein, human copper trans...

S. Rzadkosz, J. Zych, A. Garbacz-Klempka, J. Kozana, M. Piękoś, J. Kolczyk, Ł. Jamrozowicz, AGH University of Science and Technology, Faculty of Foundry Engineering, Krakow, Poland M. Kranc, Foundry Research Institute, Krakow, Poland T. Stolarczyk, Copper Museum in Legnica, Poland This paper presents research results in the field of casting technology of copper and copper alloys using the inves...

Metallic copper, which is normally considered as a contaminant in the growth of single-walled carbon nanotubes (SWNTs), was found to be an efficient catalyst to grow SWNTs under suitable conditions. It showed very high catalytic activity for the growth of both random SWNT networks and horizontally aligned SWNT arrays. Especially, high-quality SWNT arrays were obtained when monodispersed copper ...

the main aim of this research is to determine optimal leaching conditions; eh, ph and complexing agent concentrations, for recovery of copper from hydroxide sludges such as those produced by electroplating shops, metal finishers, treatment of acid mine drainage, and industrial wastewater in general. this has been preceded by a theoretical approach and numerical and computer calculation. potenti...