نتایج جستجو برای: electrode potential
تعداد نتایج: 1120103 فیلتر نتایج به سال:
In the present paper, the use of a novel carbon paste electrode modified by 7,8-dihydroxy-3,3,6-trimethyl-3,4-dihydrodibenzo[b,d]furan-1(2H)-one (DTD) and oxidized multi-walled carbon nanotubes (OCNTs) is described for determination of levodopa (LD), acetaminophen (AC) and tryptophan (Trp) by a simple and rapid method. At first, the electrochemical behavior of DTD is studied, then, the mediated...
In order to study the Cu(II) ion selective electrode, an optimized membrane was prepared by mixing of 30 mg of PVC powdered, 5 mg of considered ionophore, 60 mg of plasticizer and 5 mg of additive. The sensor showed a near Nernstian response for Cu(II) ions over a concentration range from 1.0×0-6 –1.0×0-2 M with a slope of 28.90.5 mV per concentration decade with a working pH range of 3.5-6.3. ...
The electrical response of an electrolytic cell in which the diffusion of mobile ions in the bulk is governed by a fractional diffusion equation of distributed order is analyzed. The boundary conditions at the electrodes limiting the sample are described by an integro-differential equation governing the kinetic at the interface. The analysis is carried out by supposing that the positive and neg...
Significant effects of magnetic iron oxide (Fe3O4) nanoparticles on the potentiometric behavior of carbon paste electrode for bio determination of Isoniazid aromatic drug (INH) were studied. The electrochemical performance of modified Fe3O4/CPE was investigated. The constructed Fe3O4/CPE showed high precision, sensitivity ...
The electrochemical behavior of a modified carbon paste electrode (MCPE) with N,N′ethylenbis(salicylideneiminato)copper(II) complex ([Cu(II)-Salen]) was investigated as a newsensor for cystein. The Britton-Robinson buffer with pH 5, 10% modifier in electrode, potentialscanning rate of 20 mVs-1 and puls height of 50 mV were used as the optimum condition for thedetermination of cysteine using car...
An experimental method for measurement of local redox potential within multilayer electrodes was developed and applied to all-vanadium redox flow batteries (VRFBs). Through-plane measurement at the positive side reveals several important phenomena including potential distribution, concentration distribution of active species and the predominant reaction location within the porous carbon electro...
the aqueous electrochemistry of a number of anthraquinone derivatives was studied by using cyclic voltammetry at the surface of carbon paste electrode (cpe). from measurements of the half-wave potential as a function of ph, the potential - ph diagrams were constructed for each compound. the values of formal potentials and the pk'a of some different redox and acid-base couples involved in each c...
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