reaction between 5-methyl-3-aminoisoxazole and ?-acetamidophenylsulpho-nylchloride yielded compound 1. hydrolysis of compound 1 gave a starting compound 4-methoxybenzal-?-5-methyl isoxazol-3-yl-sulphonamido aniline 2. the compound 2 on condensation with different aldehydes and potassium cyanide yielded the nitriles 3a-l. cyclocondensation between oxazolinone and compound 2 yielded imidazolines ...

starting from readily available 2-substituted-4-methylthiazole-5-carboxylic acid hydrazide (1), the title compounds were prepared. the reaction of compound 1 (r=ch3) with formic acid yielded 1-(formyl)-2-(2,4-dimethylthiazole-5-carboxyl) hydrazine (2). refluxing the latter with phosphorous pentasulfide in xylene afforded compound 3, the reaction of compound 2 with phosphorous pentoxide afforded...

elastomer compound based on nr/br was prepared using different kinds of nano-zno and zno. the effect of zinc oxide as an activator of sulfur cure on the mechanical and morphological properties of the compound was studied. the result of the mechanical properties showed that the tensile strength, elongation-at-break, resilience, and abrasion resistance of the compound prepared by zno (4 phr) are ...

NBO analysis and density functional theory (DFT: B3LYP/6-311+G**) based method were used to study the impacts of the anomeric effects (AE) on the conformational properties of 2-methoxy-1,2,4,5-tetrahydro-benzo[d]oxepine (1), -thiepine (2) and -selenepine (3). The Gibbs free energy difference (Geq–Gax) values (i.e. ΔGeq-ax) at 298.15 K and 1 atm between the axial and equatorial conformations inc...