[Purpose] We compared ankle temporal motor coordination between stroke, spinal disease and healthy elderly groups, and investigated the relationship between motor impairments and gait speed. [Subjects] Twenty-four patients with stroke, 19 post-operative spinal disease patients and 17 healthy elderly subjects participated. [Methods] Ankle temporal motor coordination of the three groups was asses...

The reaction of the thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile ligands afforded four Ag(i) coordination polymers with excellent photocatalytic activity in degradation mordant blue 9 dye.

In this study, a density functional theory (DFT) study has been carried out to investigate the mechanisms of Rh(I)-catalyzed carbenoid carbon insertion into a C-C bond reaction between benzocyclobutenol (R1) and diazoester (R2). The calculated results indicate that the reaction proceeds through five stages: deprotonation of R1, cleavage of the C-C bond, carbenoid carbon insertion, intramolecula...

Energy is the substance foundation of human society. Single−atom catalysts (SACs) have emerged as promising electrode materials in energy field owing to their unique characteristics. It was demonstrated that hydrogen evolution reaction (HER) performance SACs relies on metal−centric species and corresponding local coordination engineering. Herein, recent progress relating asymmetric atomic for H...