The formation of carbonaceous deposits (coke) in zeolite pores during catalysis leads to temporary deactivation of catalyst, necessitating regeneration steps, affecting throughput, and resulting in partial permanent loss of catalytic efficiency. Yet, even to date, the coke molecule distribution is quite challenging to study with high spatial resolution from surface to bulk of the catalyst parti...

OBJECTIVE This study aimed to assess the impact of in vitro erosion provoked by different cola-based drinks (Coke types), associated or not with toothbrushing, to bonding to enamel. MATERIAL AND METHODS Fifty-six [Corrected] bovine enamel specimens were prepared and randomly assigned into seven groups (N=8): C- Control (neither eroded nor abraded), ERO-RC: 3x/1-minute immersion in Regular Cok...

OBJECTIVES The objective of this study was to assess sperm quality and deoxyribonucleic acid (DNA) integrity of coke oven workers exposed to polycyclic aromatic hydrocarbons (PAHs) as compared to control subjects. MATERIAL AND METHODS The coke oven workers (N = 52) and administrative staff (N = 35) of a steel plant served as the exposed and control groups, respectively. Exposure to PAHs was a...

Petroleum coke is processed into calcined coke in a rotary kiln, where the temperature profiles of flue gas and coke bed are highly nonuniform due to different flow and combustion mechanisms. Motivated by saving energy costs, the effect of refractory brick's thermal properties on potential energy savings is investigated. This study focuses on investigating potential energy savings by replacing ...

Plastic wastes, lube oils and coal-tar are evaluated, individually and combined, as additives to coal blends for the production of blast-furnace coke. The effects of adding 2 wt% of potential additives or their mixtures (50:50 w/w) on the coking capacity of coal, the pressure generated during the coking process and the coke quality parameters were evaluated. Using a combination of polyolefin wa...

OBJECTIVES It was reported previously that topside oven workers with heavy exposure to coke oven emissions had increased serum activities of hepatic aminotransferase in one coke oven plant. This study was conducted to investigate the modifying effect of CYP1A1 MspI polymorphism on liver function profiles in coke oven workers. METHODS 88 coke oven workers from a large steel company in Taiwan w...

This paper provides background to the coke strength after reaction (CSR) test and gives perspective regarding changes in the cokinp coal market. It provides it sumtnary of some of the predicted relationships hctween the ash chemistry of coal, and coke properties of British Columbia coals. A brief overview iIf the ash chemistry of British Columbia coking coals is presented. The data arc used to ...

This study aimed to evaluate the effect of beers on the bovine enamel microhardness. Fifty rectangular (1 x 3 x 1 mm-height x width x thickness) enamel specimens were obtained from permanent bovine incisors, and divided into five groups (n = 10) according to the treatment employed: Saliva, Coke, Brahma, Heineken, and Budweiser. Microhardness (Knoop) were obtained before; after 5, 30 and 60 min ...

Catalytic and noncatalytic copyrolysis of plastic heavy oil was studied using thermogravimetric analysis (TGA), pyrolysis reactor experiments, GC the formed liquid. As revealed by TGA predegradation as a pretreatment method had further lowered decomposition temperature polypropylene– (PP?) bitumen mixtures reduced severity catalyst deactivation coke. The presence PP in increased liquid yield de...

A study was conducted to evaluate the effect of reaction pressure on the toluene disproportionation reaction using ZSM-5 zeolite based catalyst impregnated with molybdenum. Results showed that there is a marked difference in toluene conversion and xylenes selectivity using nitrogen and hydrogen carrier gases and the reaction pressure. Toluene conversion under nitrogen pressure was higher than u...