An efficient synthesis of chromenylphenylpropanone derivatives as warfarine-like analogues was developed by the Michael addition of 4-hydroxycoumarin to α,β-unsaturated compounds in the presence of polyvinylpolypyrrolidone supported antimony(III) chloride (PVPP-SbCl3) as a new polymeric Lewis acid catalyst in chloroform at reflux conditions without formation of 2,4-...

An economical and environmental friendly method has been developed for the synthesis of Schiff base ligand N,N'bis(2-hydroxy-1-naphthylidene)-4-hydroxyphenylmethanediamine by one pot three components reaction of 2hydroxy-1-naphthaldehyde , 4-hydroxy benzaldehyde and ammonium acetate salt in the presence of triethyl amine under solvent free condition at room temperature. Cu(II), Ni(II) and Zn(II...

A theoretical study was conducted to investigate the chemical nature of an unusual interaction observed between carbonyl and acetate ligands in theRh(CO)2(CF3COO)3 complex. This interaction is intriguing because it is only nominally longer (0.1-0.2 Å) than a typical carbon-oxygen σ bond, yet is associated with only a modest (∼10 kcal/mol) energy lowering of the complex. A localized bonding mole...

In this research, some of the inorganic complexes of uranyl with N- donor ligandswere synthesized. Complexes were characteriezed by FT-IR and UV spectra, ¹HNMR,¹³CNMR and some physical properties. The uranyl unit (UO2) is composed of a center ofuranium atom with the charge (+6) and two oxygen atom by forming two U=O double bonds.The structure is linear (O=U=O, 180) and usually stable. So other ...

A highly practical and efficient preparation of 3,4-Dihydropyrimidin-2(1H)-one derivatives was developed via an efficient and simple nanocatalyst and promoted multi-component reaction of ethyl acetoacetate, aromatic aldehyde, and urea in the presence of a catalytic amount of (CTA)3[SiW12]-Li+-MMT under solvent-free conditions. In comparison to the conve...

Quinoline derivatives have been reported to possess multi-therapeutic potential owing the manifestations of different pharmacological effects. The current research work describes about design and synthesis a series novel benzoquinoline analogues with an objective evaluate their antiproliferative structure–activity relationship against colon, breast hepatocellular cancers. Upon synthesis, all de...

Two novel urea anion receptors (11) and (12) were synthesized from building block 3,3’ methylene diamine and was characterized via the techniques of 1H NMR, 13 C NMR, DEPT135 1H-1H COSY, HMQC and HMBC spectroscopy. The 1H NMR profile of both compounds reveals diagnostic peaks. For compound (11), the urea NH protons resonate as two singlets downfield at 8.706 ppm and 8.635 ppm, whereas for compo...

Given the growing interest in the production of new and low cost bioemulsifiers, the rice and wheat bran and straw were investigated in this study for the production of bioemulsifier by Lactobacillus plantarum subsp. plantarum PTCC 1896 (probiotic). The strain produced bioemulsifier only in the rice bran hydrolysate medium. The bioemulsifier amount reached around 0.7 g L for 72 hours of ferment...