Oscillator strengths for transitions in Cl ii and iii are derived from lifetimes and branching fractions measured with beam-foil techniques. The focus is on the multiplets at 10718 in Cl ii and 10118 in Cl iiiwhose lines are seen in spectra acquired with the Far Ultraviolet Spectroscopic Explorer. These data represent the first complete set of experimental f-values for the lines in the multiple...

The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent In(III) complex mol-ecules with similar structures and one lattice water mol-ecule. In each complex mol-ecule, the In(III) atom is six-coordinated in a distorted octa-hedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-forma...

The synthesis, spectroscopic characterization and crystal structures of new C-nitrosoaryl complexes of iridium(III) and rhodium(III) are reported. The reactions of the μ2-halogenido-bridged dimers [(η-C5Me5)IrX2]2 [X = Cl (1a), Br (1b), I (1c)] and [(η-C5Me5)RhCl2]2 (2a) with N,N-dimethyl(3) and N,N-diethyl-4-nitrosoaniline (4) yield the mononuclear complexes [(η5C5Me5)MX2(3)] [M = Ir, X = Cl (...

In the title complex, {[Nd(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the Nd(III) cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water mol-ecules in a distorted square-anti-prismatic geometry. The carboxyl-ate groups of the isonicotinate anions bridge the Nd(III) cations, forming polymeric chains running along the c axis. The Cl(-) anion is located ...

The title compound, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O]·0.5CH(3)CH(2)OH, consists of one [Fe(phen)(3)](2+) cation (phen = 1,10-phen-anthroline), one [Fe(2)Cl(6)O](2-) anion and one half-mol-ecule of ethanol. In the cation, the Fe(II) atom is coordinated by six N atoms from three phen ligands in a distorted octa-hedral geometry. In the bent anion, two Fe(III) atoms are connected by a bridging ox...

The title complex, [CoCl(C(5)H(13)N)(C(2)H(8)N(2))(2)]Cl(2)·H(2)O, comprises one chloridobis(ethyl-enediamine)(n-pentyl-amine)cobalt(III) cation, two chloride counter-anions and a water mol-ecule. The Co(III) atom of the complex is hexa-coordinated by five N and one Cl atoms. The five N atoms are from two chelating ethyl-enediamine and one n-pentyl-amine ligands. Neighbouring cations and anions...

In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol-ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol-ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol-ecule in a distorted octa-hedral geometry. Intra-mole...

The reaction of [Rh(μ-Cl)(cod)]2 with diimines, differing in their steric and electronic properties, diphenylphosphine oxide leads to the oxidative addition products, hydrido-phosphinito-Rh(III) complexes {Rh(PPh2OH)(PPh2O)(NN)(H)Cl} (1), stabilized by formation a hydrogen bonded phosphinous acid-phosphinito quasi-chelate [(PO⋅⋅⋅HOP)-κ2P]. Exchange hydride chloride afford {Rh(PPh2OH)(PPh2O)(NN)...

The kinetics of the substitution reactions between the mono-functional Au(III) complexes, [Au(dien)Cl](2+) and [Au(terpy)Cl](2+) (dien = 3-azapentane-1,5-diamine, terpy = 2,2';6',2''-terpyridine) and bi-functional Au(III) complexes, [Au(bipy)Cl(2)](+) and [Au(dach)Cl(2)](+) (bipy = 2.2'-bipyridine, dach = (1R,2R)-1,2-diaminocyclohexane) and biologically relevant ligands such as l-histidine (l-H...

In the title mononuclear iron(III) complex, [Fe(C(15)H(13)N(2)O(3))(2)]Cl·H(2)O, the Fe(III) atom has a distorted octa-hedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl(-) anions and water mol-ecules are connected into a chain along [100] through N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds. Two adjacent chains ...