The new binuclear chromium Pacman complex [Cr2(L)] of the Schiff base pyrrole macrocycle H4L has been synthesized and structurally characterized. Addition of isocyanide, C≡NR (R = xylyl, tBu), or triphenylphosphine oxide donors to [Cr2(L)] gives contrasting chemistry with the formation of the new coordination compounds [Cr2(μ-CNR)(L)], in which the isocyanides bridge the two Cr(II) centers, and...

The extraction of chromium (VI) from hydrochloric, hydrobromic, and acetic acid solutions with Tri caprylamine oxide (TCAO) in benzene has been studied. The extractions from hydrochloric and hydrobromic, acid solutions are nearly quantitative and are partial from acetic acid solutions. The optimum conditions for extraction were established from the study of the effect of several variables like–...

The kinetics of electron transfer between electrochemically passivated chromium and several outer-sphere redox couples have been investigated as a function of passive-film thickness, d = 5 to 25/~, in 1M H2SO4. The apparent rate of electron transfer decreased exponentially with increasing thickness of the passivating overlayer. Similarly, during potentiostatic film growth, the electron-transfer...

Lithium ion conductors 5. Lithium Nitride Li3N 6. Lithium Lanthanum Titanium Oxide, Li3xLa0.67-xTiO3 7. Lithium Titanium Phosphate, LiTi2(PO4)3 Sodium ion conductors 8. Sodium β-Alumina, Na2O)1+x(Al2O3)11 9. Sodium β”-Alumina, Li-stabilized, Na1.5(Li0.25Al10.75)O17 10. Sodium β-Gallate, (Na2O)*n(Ga2O3) 11. Sodium β”-Gallate, Na1.98Ga10.673 O17 12. Sodium Yttrium Silicate, Na5YSi4O12 13. Sodium ...

We have investigated the growth and reactivity of chromium layers deposited onto a thin alumina film at room temperature and at 570 K. The interaction between Cr and the Al2O3/NiAl(1 1 0) surface leads to partial oxidation to Cr2þ and Cr3þ species. Complete oxidation to Cr3þ was achieved using moderate O2 doses at room temperature in vacuum. Cr has also been deposited in an O2 background pressu...

The results of atmospheric pressure plasma treatments using diffuse coplanar surface barrier discharge (type of surface dielectric barrier discharge) on chromium surfaces are reported. A significant increase of surface wettability was observed after short plasma exposition. A quantitative value of surface wettability, i.e. the surface free energy, changed from 29 mJ/m to over 80 mJ/m. In time, ...

Oxide conversion reactions are an alternative approach for high capacity lithium ion batteries but are known to suffer from structural irreversibility associated with the phase separation and reconstitution of reduced metal species and Li2O. In particular, the morphology of the reduced metal species is thought to play a critical role in the electrochemical properties of a conversion material. H...

Samples of 53 materials that are used or potentially can be used or in the fabrication of microelectromechanical systems and integrated circuits were prepared: single-crystal silicon with two doping levels, polycrystalline silicon with two doping levels, polycrystalline germanium, polycrystalline SiGe, graphite, fused quartz, Pyrex 7740, nine other preparations of silicon dioxide, four preparat...

Using linear support vector machines, we investigated the feature selection problem for the application of all-against-all classification of a set of 20 chemicals using two types of sensors, classical doped tin oxide and zeolite-coated chromium titanium oxide sensors. We defined a simple set of possible features, namely the identity of the sensors and the sampling times and tested all possible ...