New coordination polymer of [HgLCl2]n (1) with HgCl2 and Schiff base bidentate ligand (4-methoxyphenyl) pyridine-2yl methyleneamine (L) was prepared and structurally characterized. In the 1D network structure of 1, the mecury (II) ion adopts an HgN2Cl3 distorted square pyramid geometry. In this complex, one of the chlorine acts as bridging ligand connecting two adjacent mercury(II) ions while, ...

Singlet oxygen production in the chloroperoxidase-hydrogen peroxide-halide system was studied using 1268 nm chemiluminescence. With chloride or bromide ions, singlet oxygen is produced by the mechanism (formula; see text) (formula; see text) where X- is chloride or bromide ion. Under conditions where there is high enzyme activity and when Reaction B is fast relative to Reaction A, singlet oxyge...

kashan aquifer is adjacent to salt lake. because of this adjacency, the saline water of the lake has moved to the aquifer. in this study groundwater quality of the aquifer was simulated using artificial neural network (ann) model. for this purpose, the dominant ion of water was first determined by piper diagram. results showed that the sodium chloride is the dominant ion of water and so it was ...

Nowadays, Fourier transform infrared (FT-IR) spectrometry (both extractive and open-path techniques) is widely used for the detection of air pollutants because the method is fast, reliable, and nondestructive. It is capable of detecting simultaneously all compounds except non-infrared active homonuclear diatomic molecules. Molecular chlorine gas has many anthropogenic sources, including water t...

Research shows that chloride ion in the process of chemical oxygen demand (COD) analysis has a huge impact on results analysis, How to improve accuracy presence chlorine interference is difficult problem current environmental monitoring work, This article introduces different method influence degree (COD).

The chlorite-tetrathionate reaction has been studied spectrophotometrically in the pH range of 4.65-5.35 at T = 25.0 +/- 0.2 degrees C with an ionic strength of 0.5 M, adjusted with sodium acetate as a buffer component. The reaction is unique in that it demonstrates autocatalysis with respect to the hydrogen and chloride ion products and the key intermediate, HOCl. The thermodynamically most-fa...

We have investigated electrochemical treatment of real domestic wastewater coupled with simultaneous production of molecular H2 as useful byproduct. The electrolysis cells employ multilayer semiconductor anodes with electroactive bismuth-doped TiO2 functionalities and stainless steel cathodes. DC-powered laboratory-scale electrolysis experiments were performed under static anodic potentials (+2...

A measurement system was successfully fabricated to detect ion concentrations (hydrogen and chlorine) in this study. PIC18F4520, the microcontroller was used as the control unit in the measurement system. The measurement system was practically used to sense the H and Cl in different examples, and the pH and pCl values were exhibited on real-time LCD display promptly. In the study, the measureme...

Forest filtering is a well-known and efficient method for diminishing atmospheric pollutant (such as SO42- and Cl-) inputs to soil and water; however, the filtering efficiencies of forests vary depending on the regional vegetation and climate. The rainy area of West China has suffered from heavy rainfall and human activity, which has potentially resulted in large amounts of sulfur and chlorine ...