نتایج جستجو برای: chirality
تعداد نتایج: 12872 فیلتر نتایج به سال:
Chirality in microcavities has recently shown its bright future in optical sensing and microsized coherent light sources. The key parameters for such applications are the high quality (Q) factor and large chirality. However, the previous reported chiral resonances are either low Q modes or require very special cavity designs. Here we demonstrate a novel, robust, and general mechanism to obtain ...
Light-scattering measurements of the correlation length in the isotropic phase of a nematic liquid crystal reveal a temperature dependence following Landau-de Gennes theory for the isotropic phase with a bare correlation length smaller than has been measured in other liquid crystals. Similar measurements in a cholesteric liquid crystal demonstrate that the correlation length in the isotropic ph...
Filaments which form either between or around active regions (ARs) are called intermediate filaments. In spite of various theoretical studies, the origin of the chirality of filaments is still uncovered. We investigated how intermediate filaments are related to their associated ARs, especially from the point of view of magnetic helicity and the orientation of polarity inversion lines (PILs). Th...
Achiral meteoritic amino acids, glycine and alpha-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.
in the first part of this work, correlation between optical activity and elements of magnetic susceptibility tensor (mst) for five classes of model small molecules containing a single chiral center has been studied using quantum computational techniques at dft-b3lyp level of theory with 6-311g basis set. several molecular properties are used to reduce the mst elements prior to the examination o...
A facile synthesis of optically active mono and trisubstituted calix[4]arenes is described wherein the chirality at the methylene bridges arises from centers of chirality present in the diyne and the bis-carbene complex from which they are constructed.
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