the contamination of water by toxic heavy metals is a world-wide environmental problem. discharges containing cadmium, in particular, are strictly controlled due to the highly toxic nature of this element and its tendency to accumulate in the tissues of living organisms. low concentration (below 5 mg`/l) of cadmium is difficult to treat economically using chemical precipitation methodologies. i...

The reaction of fly ash with a KOH solution was used to synthesize Linde F(K) zeolite, following which Fourier transform infrared spectroscopy were used to characterize the crystalline material. The competitive adsorption of Cu, Ni, Pb, and Cd onto this zeolite was subsequently studied in quaternary solution systems. The results show that the metal removal rates gradually increase with incr...

the interaction between some heavy metal ions such as of pb(ii), cd(ii) and cu(ii) ions from aqueous solution adsorbed by single walled carbon nanotube (swcnts) and carboxylate group functionalized single walled carbon nanotube (swcnt-cooh) surfaces were studied by atomic absorption spectroscopy. the effect of contact time, ph, initial concentration of ion, ionic strength and temperature on the...

This work was designed to understand the mechanisms of adsorption of copper (Cu) and cadmium (Cd) on roots of indica and japonica varieties of rice. Six varieties each of indica and japonica rice were grown in hydroponics and the chemical properties of the root surface were analyzed, including surface charges and functional groups (-COO- groups) as measured by the streaming potential and attenu...

Many coal-fired power plants are implementing ammonia-based technologies to reduce NO(x) emissions. Excess ammonia in the flue gas often deposits on the coal fly ash. Ammonia can form complexes with many heavy metals and change the leaching characteristics of these metals. This research tends to develop a fundamental understanding of the ammonia impact on the leaching of some heavy metals, exem...

BACKGROUND Emulsions stabilized by colloidal particles are known as Pickering emulsions. To date, soft microgel particles as well as inorganic and organic particles have been utilized as Pickering emulsifiers. Although cyclodextrin (CD) works as an attractive emulsion stabilizer through the formation of a CD-oil complex at the oil-water interface, a high concentration of CD is normally required...

Corrosion inhibitors are added in low concentrations to corrosive solutions for reducing the corrosion rate of a metallic material. Their mechanism of action is typically the blocking of free metal surface by adsorption, thus slowing down dissolution. This work uses electrochemical impedance spectroscopy to show the cyclic oligosaccharide β-cyclodextrin (β-CD) to inhibit corrosion of zinc in 0....

High-surface-area mesoporous MgO-templated nanocarbons made with reinforcing fibres from scrap tyres and a bituminous waste as carbon precursor were employed for the simultaneous adsorption of Cd and reactive Cibacron Brilliant Yellow 3G-P dye. A commercial activated carbon (AC) Darco KB-WJ was also used for comparison purposes. The effect of the pH of the solution was studied to establish whet...

Depositions of all kinds of urban dirt and dust including anthropogenic organic substances like soot change the filter properties of the seam filling material of pervious pavements and lead to the formation of a new soil substrate called seam material. In this study, the impact of the particular urban form of organic matter (OM) on the seam materials CECpot, the specific surface area (As), the ...

We have developed a simple one-step method to synthesize novel supramolecular polysaccharide composites from cellulose (CEL), chitosan (CS) and benzo-15-crown 5 (B15C5). Butylmethylimidazolium chloride [BMIm(+)Cl(-)], an ionic liquid (IL), was used as a sole solvent for dissolution and preparation of the composites. Since majority of [BMIm(+)Cl(-)] used was recovered for reuse, the method is re...