Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents.  This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania s...

A two-dimensional nanolayered polyoxomolybdate, [4,4´-H2bipy] [Mo7O22].H2O (1), where 4,4´-bipy = 4,4´-bipyridine, was prepared and characterized by FT-IR and atomic absorption spectroscopies, transmission electron microscopy (TEM), X-ray single crystal and powder diffraction (XRD), and thermogravimetric analysis. The catalytic performance of 1 was assessed in the epoxidation of some olefins em...

In this article, the catalytic activity of bis[2-(p-tolyliminomethyl)phenolato] copper(II) complex was studied, for the first time, in the oxidation of various primary and secondary alcohols to the corresponding aldehydes or ketones. The effect of different solvent was studied in the oxidation of benzyl alcohol and methanol was chosen as the reaction medium. Also the effect of different oxidant...

Grafting of 3-aminopropyltriethoxysilane (APTS) on graphene oxide (GO) nanosheets followed by reaction with phosphotungstic acid (H3PW12O40, denoted as H3PW) gave a new functionalized GO which was characterized using FT-IR, FESEM, EDX, EDX elemental mapping and ICP-OES techniques. The catalytic activity of this nanomaterial containing phosphotungstic counter-anion H2PW12O40¯ (H2PW) which was de...

Here, we report the synthesis, characterization, and catalytic evaluation of Ni-Cu-Mg ferrite using tragacanth gum as biotemplate and Metals nitrate as the metal source by the sol-gel method without using any organic chemicals. The sample was characterized by powder X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Vibrating Sample Magnetometer (VSM), and Scanning El...

Among a wide range of pollutants, organic pollutants have given rise to major environmental concerns. Various methods have been considered to mitigate the damage, including catalytic reduction to less hazardous compounds. Catalysts that benefit from high surface area and suitable surface sites for various steps of the catalytic reaction have shown outstanding results in performing such duties. ...

to improve the photo-catalytic degradation of salicylic acid, we reported the fabrication of ordered tio2 nanotube arrays by a simple and effective two-step anodization method and then these tio2 nanotubes treated in a methanol solution under uv light irradiation. the tio2 nanotubes prepared in the two-step anodization process showed better photo-catalytic activity than tio2 nanotubes prepared ...

nanometric carbid silicon (sic) supported monometallic and bimetallic catalysts containing fe, co, ni transition metals were prepared by wet impregnation method. multiwall carbon nanotubes (mwcnts) were synthesized over the prepared catalysts from catalytic decomposition of acetylene at 850°c by thermal chemical vapor deposition (tcvd) technique. the synthesized nanomaterials (catalysts and cnt...

Sulfuric acid ([3-(3-silicapropyl)sulfanyl]propyl]ester (SASPSPE) is employed as a recyclable catalyst for the silylation of hydroxyl groups. A good range of primary, secondary alcohols and phenolic hydroxyl groups were effectively converted into their corresponding trimethylsilyl ethers with hexamethyldisilazane in the presence of catalytic amounts of SASPSPE at room temperature with short rea...