The colloidal and biological properties of the two single-chain surfactants N-benzyl-N,N-dimethyl-N-(1-dodecyl)ammonium bromide (PH12) and N-cyclohexylmethyl-N,N-dimethyl-N-(1-dodecyl)ammonium bromide (CH12) and their two dimeric counterparts N,N'-(1,3-phenylenebis(methylene))bis(N,N-dimethyl-N-(1-dodecyl)ammonium dibromide (12PH12) and N,N'-(cyclohexane-1,3-diylbis(methylene))bis(N,N-dimethyl-...

Main-chain chiral quaternary ammonium polymers were successfully synthesized by the quaternization polymerization of cinchonidine dimer with dihalides. The polymerization occurred smoothly under optimized conditions to give novel type of main-chain chiral quaternary ammonium polymers. The catalytic activity of the polymeric chiral organocatalysts was investigated on the asymmetric benzylation o...

michael addition of pyrimidine and purine nucleobases to substituted as well as unsubstituted α,β-unsaturated esters efficiently proceeds in the presence of catalytic amount of zinc oxide in ionic liquid 1-butyl-3-methylimidazolium bromide (zno/[bmim]br) under microwave irradiation to afford carboacyclic nucleosides, as biologically important compounds, in good to excellent yields and in short ...

Mesoporous carbon spheres (MCS) have been fabricated from structured mesoporous silica sphere using chemical vapor deposition (CVD) with ethylene as a carbon feedstock. The mesoporous carbon spheres have a high specific surface area of 666.8 m2/g and good electrochemical properties. The mechanism of formation mesoporous carbon spheres (carbon spheres) is investigated. The important thing is a s...

1-Butyl-3-methylimidazolium bromide ([bmim]Br) as an ionic liquid promoted selectively oxidation of aliphatic and aromatic sulfides to the corresponding sulfoxides and the oxidative coupling of thiols to disulfides by NaBrO3 in excellent yields under neutral conditions.

A novel artificial peroxidase (AP) with highly catalytic efficiency was designed using hexadecyl trimethyl ammonium bromide (CTAB, 3 mM) nano-micelles and bovine heart cytochrome c (Cyt c, 0.5 µM) in 100 mM, pH 8.0 phosphate buffer at 25°C. The catalytic rate (kcat) and Michaelis-Menten (Km) of the AP were determined to be 0.311 ± 0.013 s(-1) and 8.64 ± 0.6 µM. The catalytic efficiency was 0.03...

a spectrophotometric study concerning the interactoin between iodine and bromine with tetrabutylammonium iodide (tbai), tetrabutyl- ammonium bromide (tbabr) and cryptand 222 (c222) has been performed in dichloromethane solution at 25°c. the results are indicative of the formation of tba+x3- and  c222x+x3-  through equilibrium and formation of c222x+x-  through nonequilibrium reactions. the stab...

Colorless needles of the arsenite bromide La3OBr[AsO3]2 were synthesized from ammonium dihydrogen arsenate, ammonium bromide and lanthanum oxide in an NaBr/KBr flux at 900 ◦C. La3OBr[AsO3]2 crystallizes with the centrosymmetric tetragonal La3OCl[AsO3]2 type, space group P42/mnm. The structure was refined from single-crystal diffractometer data: a = 13.0431(15), c = 5.6127(7) Å, wR2 = 0.0454, 94...