Many industrial applications of protonic zeolites as solid-acid heterogeneous catalysts rely on the strength or their Br nsted acidity, which (together with zeolite topology) affects both, catalytic activity and selectivity. Therefore, convenience to have an accurate (and simple) experimental technique for measuring acid strength. The enthalpy change, Delta H 0 , corresponding hydrogen bonding ...

The interaction between methanol and the Heulandite-type zeolite has been unveiled to give an atomic scale detail regarding catalytic activity of this for conversion. study was carried out by first principle molecular dynamics get insight into structure electronic behaviour inside at different temperatures. studied when location proton Bronsted acid sites varied both possible direct less with m...

Growing CO2 emissions lead to global warming, which is currently one of the most challenging environmental phenomena. Direct catalytic hydrogenation dimethyl ether over hybrid catalysts enables utilization, hydrogen and energy storage produces sustainable fuels an important platform molecule. In this paper, we evaluated structure–performance correlations in bifunctional copper–zinc SAPO-34 for ...

The reaction of levulinic acid production from glucose has a stage that requires high temperature and activation energy so in this catalyst is needed. required must have lewis site bronsted the acidity very influential for successful levulonic acid. Silica nickel phosphate catalysts sites Ni metal phosphoric silica groups. was measured using pyridine ammonia adsorption method center strength TG...

The conversion of used lubricating oil towards fuel by catalytic is a suitable way to recycle waste oil. Catalyst has key role in conversion. Therefore this research was study the cracking oil, and thus its properties as an alternative for over aluminum fosfate. experiments were carried out batch microreactor at temperature 350-400 oC, atmospheric initial air pressure, 5% w/w catalyst concentra...

in this work, the ionic liquid triethylamine-bonded sulfonic acid {[et3n–so3h]cl}, n,n-diethyl-n-sulfoethanammonium chloride was used as a green acidic homogeneous catalyst to synthesis of 3,4-dihydropyrimidin-2(1h)-ones and 3,4-dihydropyrimidin-2(1h)-thiones as two categories of heterocycles, from aldehyde, dicarbonyl compound and urea or thiourea throughout the one-pot three components cycloc...

Nonionic hydrazine reacts with anionic bis(2,4-dinitrophenyl) phosphate (BDNPP), giving 2,4-dinitrophenyl hydrazine and dianionic 2,4-dinitrophenyl phosphate by an S(N)2(Ar) reaction, and at the phosphoryl center, giving 2,4-dinitrophenoxide ion and a transient phosphorylated hydrazine that rearranges intramolecularly to N-(2,4-dinitrophenyl)-N-phosphonohydrazine. Approximately 58% of the react...