The structural and electronic properties of nickeland phosphorus-doped boron–carbon (B5C) alloy thin films grown by plasma-enhanced chemical vapor deposition have been examined. The Ni-doped boron–carbon alloys were grown using closo-1,2-dicarbadodecaborane (C2B10H12) as the boron–carbon source compound and nickelocene (Ni(C5H5)2) as the nickel source. The phosphorus-doped alloys were grown usi...

Boron−carbon (BxC) thin films are potential neutron converting layers for B-based neutron detectors. However, as common material choices for such detectors do not tolerate temperatures above 500 °C, a low temperature deposition route is required. Here, we study trimethylboron B(CH3)3 (TMB) as a single-source precursor for the deposition of BxC thin films by plasma CVD using Ar plasma. The effec...

Porous polymers, integrating the advantages of porous materials and conventional polymers, have been well developed and exhibited tremendous attention in the fields of material, chemistry and biology. Of these, boron-containing conjugated porous polymers, featuring tunable geometric structures, unique Lewis acid boron centers and very rich physical properties, such as high specific surface, cha...

General remarks on the structure and the lattice vibrations o f the different structure groups o f boron and icosahedral boron-rich borides are made. In detail, the lattice vibrations o f the alpha-rhombohedral boron structure group are systematically investigated by group theory. Reflectivity spectra o f boroncarbide o f different chemical com position and preparation and o f B60 were measured...

The essentiality of boron for higher plants was demonstrated (1) in 1910 and extensively verified in the two succeeding decades. Since then a voluminous literature has accrued concerning the anatomical, morphological, and biochemical alterations of boron-deficient plants. Inasmuch as they are not pertinent to the following report, many of the specific or general roles that have been postulated ...

Carbon dioxide released by arc volcanoes is widely considered to originate from the mantle and from subducted sediments. Fluids released from upper arc carbonates, however, have recently been proposed to help modulate arc CO2 fluxes. Here we use boron as a tracer, which substitutes for carbon in limestone, to further investigate crustal carbonate degassing in volcanic arcs. We performed laborat...

We present a detailed study of B1-xNx (0<x<0.6) films synthesized at room temperature by N2 + ion-beam assisted evaporation of boron. The atom-ion ratio was related to the final boron concentration as determined by X-ray energy dispersive spectroscopy (XEDS), and to the bonding structure explored by infrared (IR) and X-ray absorption near-edge structure (XANES) spectroscopies. IR and XANES reve...

The role of bicarbonated mineral waters on lipid metabolism and lipoprotein concentrations in man has scarcely been investigated. The present study aimed to investigate whether drinking sodium bicarbonated mineral water affects postprandial cholesterol and triacylglycerol metabolism in postmenopausal women. In a three-way, randomised, crossover study, eighteen healthy postmenopausal women consu...