16 Groundwaters at nuclear sites are often characterised by low pH and high nitrate 17 concentrations (10-100 mM). These conditions are challenging for bioremediation, often 18 inhibiting microbial Fe(III)-reduction that can limit radionuclide migration. Here, sediment 19 microcosms representative of the UK Sellafield site were used to study the influence of 20 variable pH and nitrate concentra...

Silver nanoparticles with size of 6- 57nm were synthesized by bioreduction method from Anisochilus carnosus aqueous and ethanolic extract. Biosynthesized nanoparticles showed maximum antimicrobial activity against K. pneumonia (13±1.67mm), E.coli (13±1.97mm) and B. subtilis (13±1.07mm) followed by P. aeruginosa and minimum against <...

Hydrophilic ionic liquids (ILs) were employed as green solvents to construct an IL-containing co-solvent system for improving the asymmetric reduction of 4-(trimethylsilyl)-3-butyn-2-one by immobilized Candida parapsilosis cells. Among 14 hydrophilic ILs examined, 1-(2'-hydroxyl)ethyl-3-methylimidazolium nitrate (C(2)OHMIM·NO(3)) was considered as the most suitable IL for the bioreduction with ...

Methanobactin (Mb) is a copper-binding peptide that appears to function as an agent for copper sequestration and uptake in methanotrophs. Mb can also bind and reduce Au(III) to Au(0). In this paper, Au/Al2O3 catalysts prepared by a novel incipient wetness-Mb-mediated bioreduction method were used for glucose oxidation. The catalysts were characterized, and the analysis revealed that very small ...

Bioreduction-based strategies for remediating uranium (U)-contaminated sediments face the challenge of maintaining the reduced status of U for long times. Because groundwater influxes continuously bring in oxidizing terminal electron acceptors (O2, NO3(-)), it is necessary to continue supplying organic carbon (OC) to maintain the reducing environment after U bioreduction is achieved. We tested ...

Medicinal plants serve as rich sources of diverse bioactive phytochemicals that might even take part in bioreduction and stabilization of phytogenic nanoparticles with immense therapeutic properties. Herein, we report for the first time the rapid efficient synthesis of novel platinum-palladium bimetallic nanoparticles (Pt-PdNPs) along with individual platinum (PtNPs) and palladium (PdNPs) nanop...