The authors studied the direct conversion of syngas to light paraffins in a dual-bed fixed-bed reactor. A catalyst composed three catalysts, physically mixed methanol synthesis (CZA), and dehydration dimethyl ether (DME) (Al2O3(C)) were put upper bed for DME, while SAPO-34 (SP34-C) zeolite was lower DME conversion. effects mass ratio CZA Al2O3(C), H2/CO molar ratio, space velocity on catalytic ...

Abstract This study investigates the production of diesel fuels by integrated Fischer–Tropsch synthesis over a bifunctional cobalt catalyst consisting component (Co–Al 2 O 3 /SiO ) and zeolite-containing (ZSM-5). The catalytic properties were tested in continuous-flow reactor with stationary bed at 240–250°C, MPa, gas WHSV 1000 h –1 . effects SiO /Al ratio HZSM-5 zeolite on performance, deactiv...

Abstract:  In this study adiffusion based mathematical model was developed to compare the performance of amine-grafted adsorbents with that of 13X zeolite in a fixed-bed adsorption tower which is used to capture CO2 from both humid and dry nitrogen stream under industrial conditions. The results show that the performance of amine-grafted adsorbent and 13X zeolite is almost the same in the dry ...

in this paper, experimental data on the drying kinetics of corn in a packed and fluidized bed are presented. experimental research was conducted on a laboratory apparatus. corn was used as a material because of its significance in agriculture and the food industry. an analysis of the influence of the operational parameters (the drying medium velocity i. e. the fluidization number, the drying me...

Two different fly ash (FA) samples were tested for their ability to give synthetic zeolitic products. Polish bituminous (PB) and South African (SA) coal fly ash (FA) samples, derived from pilot-scale circulated fluidized bed (CFB) combustion facilities, have been utilized as raw materials. The two FAs underwent a hydrothermal activation with 1M NaOH solution at 90°C for 24 h. Two different FA/N...

Nanosized zeolite crystals (nanozeolites) with narrow particlesize distributions and sizes less than 100 nm have received much attention because of their great potential applications in catalysis and adsorption. The decrease in the crystal sizes results in high external surface areas, reduced diffusion path lengths, and more exposed active sites. For example, small Y-type zeolite crystals have ...

Fast (>I2 kHz) magic-angle-spinning NMR with IH' 7AI cross-polarization quantitatively monitors several aluminous species in dealuminated zeolite Y; the non-framework matter contains 4-, 5-and 6-coordinated A1 and the *7AI signal at 30 ppm is an independent resonance probably due to 5-coordinated non-framework Al and not part of a second-order quadrupole lineshape as previously reported. Since ...

Bandshape luminescence thermometry during in situ temperature measurements has been reported by preparing three catalytically relevant systems, which show temperature-dependent luminescence. One of these systems was further investigated as a showcase for application. Microcrystalline NaYF4 doped with Er3+ and Yb3+ was mixed with a commercial zeolite H-ZSM-5 to investigate the Methanol-to-Hydroc...

Development of cost-effective amendments for treating dairy slurry has become a critical problem as the number of cows on farms continues to grow and the acreage available for manure spreading continues to shrink. To determine effectiveness and optimal rates of addition of either alum or zeolite to dairy slurry, we measured ammonia emissions and resulting chemical changes in the slurry in respo...

In this research, adsorption of dibenzothiophene (DBT) as a model of sulfur containing material has been studied by Pb exchanged Y-zeolite under different experimental conditions. The adsorption was kinetically fast and high adsorption capacity was obtained. The equilibrium adsorption data were analyzed using Langmuir and Freunlich isotherm models. The corresponding parameters and correlation c...