•Unique axial-to-axial chirality transfer for C–N axial construction•Ability to assemble two vicinal and remote stereogenic axes•Step-economic scalable synthesis of enantioenriched phenanthridinones•Broad scope, good yields, excellent enantioselectivities Axial widely exists in bioactive natural products, pharmaceuticals, chiral materials, ligands catalysts asymmetric catalysis. As such, the ef...

hartree-fock (hf) and density functional theory (dft) methods employed to study the effect of conformational change on the 13c chemical shifts of 6-mono axial and equatorial substituted and 6,7-di axial-axial, equatorial-equatorial and axial-equatorial substitutedderivatives of 5,6,7,8-tetrahydrodibenzo[a,c]cyclo-octene. the geometry of the conformers have been optimized in the gas phase employ...

the effect of axial deformation of shell particles on the dynamic instability (flutter) of cantilevered cylindrical shells made of functionally graded materials (fgm) under an end axial follower force is addressed. to this end, at first, results for free vibration of fgm cylindrical shells were verified with previous outcomes and they were in very good agreement. then, the effect of axial defor...

the conformational behaviors of 2,3-bis(methylthio)-1,4-dioxane (1), 2,3-bis(methylthio)-1,4-dithiane (2) and 2,3-bis(methylthio)-1,4-diselenane (3) have been analyzed by means ofhybrid-density functional theory (b3lyp/def2-tzvpp) based method and nbo interpretation.b3lyp/def2-tzvpp results showed that the axial conformations of compounds 1-3 are morestable than their equatorial conformations. ...

Fungal infection of bone by Penicillium marneffei is rare. We report on a case of Penicillium marneffei infection in a Filipino woman, which involved multiple soft-tissue abscesses and infection of the axial skeleton. Early diagnosis and treatment of this potentially reversible disease is emphasised. Such an approach is essential to prevent bony destruction from becoming too advanced and, more ...

in this study, the stability problem of a circular orthotropic cylindrical shell under the effect of anaxial compression varying with a power function of time is considered. at first, the modified donnell typedynamic stability and compatibility equations are obtained using love’s shell theory. applying the galerkinmethod and rayleigh-ritz variational techniques to these equations and taking the...

in this research, softening and ratcheting behaviors of ck20 alloy steel cylindrical shells were studied under displacement-control and force-control cyclic axial loading and the behavior of hysteresis curves of specimens was also investigated. experimental tests were performed by a servo-hydraulic instron 8802 machine. the mechanical properties of specimens were determined according to astm e8...

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