•A fully ?-conjugated molecular cage was synthesized in a simple way•Chemical oxidation led to 3D globally aromatic cage•All five types of 2D macrocycles along the skeleton are Hückel aromatic•A close relation between ?-aromaticity and established Aromaticity is vital concept organic chemistry ?-/?-conjugated molecules have intrinsic tendency become via electron delocalization. Although there b...

Aromaticity is one of the most important concepts in organic chemistry. A variety of metalla-aromatic compounds have been recently prepared and in most of those examples, the metal participates only in a monocyclic ring. In contrast, metal-bridged bicyclic aromatic molecules, in which a metal is shared between two aromatic rings, have been less developed. Herein, we report the first metal-bridg...

The synergy of aromatic gain and hydrogen bonding in a supramolecular polymer is explored. Partially aromatic bis(squaramide) bolaamphiphiles were designed to self-assemble through a combination of hydrophobic, hydrogen-bonding, and aromatic effects into stiff, high-aspect-ratio fibers. UV and IR spectroscopy show electron delocalization and geometric changes within the squaramide ring indicati...

An aromatic amino acid is present in the binding site of a number of sugar binding proteins. The interaction of the saccharide with the aromatic residue is determined by their relative position as well as orientation. The position-orientation of the saccharide relative to the aromatic residue was found to vary in different sugar-binding proteins. In the present study, interaction energies of th...

ethiopia is remarkably rich in its biological, ecological and landscape diversity and is home to outstanding natural bio-resources such as a number of herbs, aromatic and medicinal plants. the present study was carried out to study the composition, distribution and economic importance of insect pests of prioritized aromatic (mentha sp., lemon verbena, fennel, rosemary, rosadamascene, oregano, p...

the essential oils and aromatic water, known as arak in traditional iranian medicine, comes from the aerial part of teucrium persicum boiss., which is grown in fars province located in iran. the samples were collected in summer and the oils and aromatic water were obtained through steam distillation. the chemical composition of the oils was analyzed using gc-ms. an analysis of the chemical prof...

vehicle exhaust is a major source of exposure to polycyclic aromatic hydrocarbons (pahs) found in the urban atmosphere. newsagents usually work close to heavy traffic flow. the purpose of this study was to assess the breathing zone exposure of newsagents to pahs found in the urban atmosphere of tehran city during summer and autumn seasons and comparing the levels of exposure in both seasons.fif...

a simple extremely fast and efficient approach for the synthesis of substituted indazole ingood to excellent yield catalyzed by using silica sulfuric acid (ssa) in dmso solvent at roomtemperature. this is solid state reaction have been attracting the synthetic organic chemist asthey provided enhance reaction rates, less environmental pollution, greater selectivity, cleanerproducts and manipulat...

perylene and penta-aromatic hydrocarbons were determined in sediments as part of a study that was dedicated to the aquatic ecosystem of oginigba creek (southern nigeria) in order to carry out a critical corroboration of occurrence and diagenetic evolution of perylene in the sediments of the creek. the results show that the annual mean levels of perylene ranged from 396.27– 507.19 mg/g dry wei...

polycyclic aromatic hydrocarbons (pahs) are toxic pollutants released by various urban combustion sources. tehran is the largest city in iran with a population of about 8 million and it is faced with serious air quality problems. the gas phase samples collected from 21 sites in tehran area throughout year 2005. the samples‘ pahs were collected using a skc trapping consisting of glass cartridg...