We have performed mixed quantum-classical molecular dynamics simulations of the relaxation of a ground state excess electron at interfaces of different phases of water with air. The investigated systems included ambient water/air, supercooled water/air, Ih ice/air, and amorphous solid water/air interfaces. The present work explores the possible connections of the examined interfacial systems to...

In the perspective of a sustainable urban planning, it is necessary to investigate cities in a holistic way and to accept surprises in the response of urban environments to a particular set of strategies. For example, the process of inner-city densification may limit air pollution, carbon emissions, and energy use through reduced transportation; on the other hand, the resulting street canyons c...

In April 1995, the US Geological Survey began a study to determine the occurrence and temporal distribution of 49 pesticides and pesticide metabolites in air and rain samples from an urban and an agricultural sampling site in Mississippi. The study was a joint effort between the National Water-Quality Assessment and the Toxic Substances Programs and was part of a larger study examining the occu...

Quality evaluation of urban environment is an integral part of efficient urban environment planning and management. The development of fuzzy set theory (FST) and the introduction of FST to the urban study field attempts to incorporate the gradual variation and avoid loss of information. Urban environmental quality assessment pertain to interpretation and forecast of the urban environmental qual...

introduction recently, the presence of residents and their behavior in the urban space have become so important that manycontemporary urban theorists view the presentera as the “turn of urban space and what is happening in it”. the importance of urban behaviors and activities could be discussed from different points of view. in the contemporary literature of urban design, the mutual interaction...

An air-stable eight-coordinate (8C) Mn(II)N(8) complex has been synthesized utilizing an N(4) imidazole/imine ligand. The 8C dodecahedral geometry is structurally robust as the Mn complex is stable to air, NO(g), and potential coordinating anions. The structural, spectroscopic and water relaxivity properties of this complex are reported.

Urbanisation leads to increased thermal stress in hot-humid climates due to increased surface and air temperatures and reduced wind speed. We examined the influence of urban morphology and sea breeze on the microclimate of Colombo, Sri Lanka. Air and surface temperatures, humidity and wind speed were measured at 1 rural and 5 urban sites during the warmest season. The urban sites differed in th...

Introduction Conclusions References Tables Figures Back Close Abstract Introduction Conclusions References Tables Figures Back Close Abstract The quality of the urban air pollution forecast critically depends on the mapping of emissions, the urban air pollution models, and the meteorological data. The quality of the meteorological data should be largely enhanced by using downscaled data from ad...

The quality of the urban air pollution forecast critically depends on the mapping of emissions, the urban air pollution models, and the meteorological data. The quality of the meteorological data should be largely enhanced by using downscaled data from advanced numerical weather prediction models. These different topics, as well as the application of population exposure models, have traditional...