Molecular dynamics simulations are used to model the evaporation of a Lennard–Jones argon nanodroplet into its own vapor for a wide range of ambient temperatures and ambient pressures. The transitions from i high to low Knudsen number evaporation and ii subcritical to supercritical evaporation are observed. At a low ambient pressure of 0.4 MPa, the initial droplet Knudsen number is 1 and the dr...