Cation adsorption data using MnCl2 and the proton isotherm of a Si oxide were compared with pH as the variable. The cation adsorption data quantitatively correlated with the proton isotherm analysis; the H+/Mn* exchange ratio was 6.0. The presence of adsorption plateaus are due to pH-dependent (step) reactions; this was suggested as the only reasonable explanation for adsorption isotherms cover...

Separation of Pb2+ from Cu2+-Pb2+ mixed solution by a newly-developed ion separating agent was examined, which was obtained by clothing chitin whiskers (ChW) on the surface of potassium tetratitanate whiskers (PTW). The separation capability and mechanism of the ion separating agent (ChW-PTW) was determined, based on the difference of the adsorption isotherm pattern and the adsorption kinetics ...

Using a combination of density functional theory and lattice models, we study the effect of CO2 adsorption in an amine functionalized metal-organic framework. These materials exhibit a step in the adsorption isotherm indicative of a phase change. The pressure at which this step occurs is not only temperature dependent but is also metal center dependent. Likewise, the heats of adsorption vary de...

The need to clean-up heavy metal contaminated environment can not be over emphasized. This paper describes the adsorption isotherm studies of Cd (II), Pb (II) and Zn (II) ions from aqueous solution using unmodified and EDTA-modified maize cob. Maize cob was found to be an excellent adsorbent for the removal of these metal ions. The amount of metal ions adsorbed increased as the initial concentr...

Sorption-based heat transformation and storage appliances are very promising for utilizing solar heat and waste heat in cooling or heating applications. The economic and ecological efficiency of sorption-based heat transformation depends on the availability of suitable hydrophilic and hydrothermally stable sorption materials. We investigated the feasibility of using the metal-organic frameworks...

The adsorption characteristics of 4-chloro-2-nitrophenol (4C2NP) onto single-walled and multi-walled carbon nanotubes (SWCNTs and MWCNTs) from aqueous solution were investigated with respect to the changes in the contact time, pH of solution, carbon nanotubes dosage and initial 4C2NP concentration. Experimental results showed that the adsorption efficiency of 4C2NP by carbon nanotubes (both of ...

In this paper, the ability of coconut bunch waste (CBW), an agricultural waste available in large quantity in Malaysia, to remove basic dye (methylene blue) from aqueous solution by adsorption was studied. Batch mode experiments were conducted at 30 degrees C to study the effects of pH and initial concentration of methylene blue (MB). Equilibrium adsorption isotherms and kinetics were investiga...

High surface area and highly mesoporous activated carbon fibers (ACF) were obtained by physical activation of natural precursors (vetiver roots and bagasse) with steam and chemical activation using phosphoric acid. The textural characteristics of the activated were determined by nitrogen adsorption study and mercury porosimetry and showed that interesting porosity were obtained (SBET up to 1600...

the work focuses on the removing of cu(ii) from aqueous solution by linde f(k) zeolite. the zeolite is synthesized from fly ash by hydrothermal process. the adsorption experiments discuss several factors including the optimal solution ph, zeolite dosage, adsorption temperature, adsorption kinetics and adsorption isotherm equation. the results show that, the optimal solution ph is 6 and the effi...