The study of the effectiveness of several potential copper corrosion inhibitors in acidic media was studied. The investigated thiazole derivative functional groups contain heterocyclic atoms such as nitrogen, sulfur, and oxygen. Thiazole derivatives, 5-benzylidene-2,4-dioxotetrahydro-1,3-thiazole (BDT) 5-(4′-isopropylbenzylidene)-2,4-dioxotetrahydro-1,3-thiazole (IPBDT), 5-(3′-thenylidene)-2,4-...

Screen printed electrodes (SPEs) have been prepared in the Biosensor Lab @ ENEA, according to different layouts and configurations, i.e. front-back or concentric geometry. Different pastes and composition have been tested depending on the application and requirements for flow or batch measurements. In order to optimize the quality of the electrochemical response, graphite pastes and metal doped...

Abstract Electrodeposition of nickel from slightly acidic gluconate solutions containing chloride or/and sulfate ions was investigated. Electrochemical measurements correlated with bath speciations showed complex and complexes as crucial species affecting cathodic reactions in a potential range up to ?1.3V. At more negative potentials, deposition governed by release cation nickel-gluconate comp...

Two α-MnO2 crystals with caddice-clew-like and urchin-like morphologies are prepared by the hydrothermal method, and their structure and electrochemical performance are characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), galvanostatic cell cycling, cyclic voltammetry, and electrochemical impedance spectroscopy (EIS). The morphology of the MnO2 prepared under acidic con...

A series of homo- and hetero-tri(aryl)boranes incorporating pentafluorophenyl, 3,5-bis(trifluoromethyl)phenyl, and pentachlorophenyl groups, four of which are novel species, have been studied as the acidic component of frustrated Lewis pairs for the heterolytic cleavage of H2. Under mild conditions eight of these will cleave H2; the rate of cleavage depending on both the electrophilicity of the...

Dispersion of 2D carbon nitride (C3N4) nanosheets into a nickel phosphorous (NiP) matrix was successfully achieved by ultrasonication during the electroless plating of NiP from an acidic bath. The morphology and thickness, elemental analysis, phases, roughness, and wettability for as-plated and heat-treated nanocomposite were determined by scanning electron microscopy, energy-dispersive X-ray s...

The corrosion inhibition of mild steel in 1 M HCl solution by some dihydropyridine has been studied using gravimetric, electrochemical impedance spectroscopy, potentiodynamic polarization techniques and quantum chemical study. results weight loss Tafel measurements showed that among the compounds, Isradipine good inhibiting properties for acidic bath, with 98% efficiency at optimum concentratio...

The cerium(IV)-alcohol couple in an acidic medium is an example of a redox system capable of initiating free radical polymerization. When the alcohol has a polymeric nature, the outcome of such a process is a block copolymer, a member of a class of compounds possessing many useful properties. The most common polymer with a terminal -OH group is poly(ethylene glycol) (PEG); however, the detailed...

Combining dental ceramics with other prosthetic metallic restorations might release metal ions, thus affecting the oral tissues of patients. In this study, we evaluated electrochemical solubility various in a galvanic experimental setup vitro. Smooth and rough feldspathic zirconium dioxide (at pH 5.5 3.0) were exposed to an electric field. Calcium, barium, selected as parameters determine both ...

We hypothesized that differences among individuals in reflux-induced oxidant production by esophageal squamous epithelial cells might contribute to the development of Barrett's esophagus. We studied the effects of acid and bile acids on the production of reactive oxygen species (ROS) in esophageal squamous cell lines derived from gastroesophageal reflux disease patients with (NES-B3T) and witho...