نتایج جستجو برای: acetylene hydrochlorination

تعداد نتایج: 3565  

Journal: :Physical chemistry chemical physics : PCCP 2009
Emma K Gibson John M Winfield Kenneth W Muir Robert H Carr Archie Eaglesham Angelo Gavezzotti Stewart F Parker David Lennon

The hydrochlorination of 4-benzylaniline in chlorobenzene to produce 4-benzylaniline hydrochloride has been examined. This has required spectroscopic and computational analysis of the solvation of gaseous HCl in the process solvent. The characterisation of the reagent and product of the hydrochlorination reaction by various techniques, including FTIR and (1)H NMR spectroscopy and X-ray diffract...

Journal: :Physical chemistry chemical physics : PCCP 2014
Junjie Gu Qian Du You Han Zhenghua He Wei Li Jinli Zhang

In order to disclose the reason that the N-doped carbon support can enhance the stability of Au-based catalysts for acetylene hydrochlorination, we established a big graphene cluster model of C110H28 to investigate the effect of different nitrogen-doped carbon supports on three kinds of gold species models of Au dimers, Au2Cl2 and Au2Cl6, through DFT calculations. Comparing the adsorption energ...

2012
Marco Conte Catherine J. Davies David J. Morgan Thomas E. Davies Albert F. Carley Peter Johnston Graham J. Hutchings

The effect of gold oxidation state and carbon structure on the activity of Au/C catalyst for the hydrochlorination of acetylene was investigated by a combined approach using TPR, XPS and porosimetry determinations. The activity of the catalyst in the synthesis of vinyl chloride monomer was found to be dependent from the presence of Au 3+ species into the catalyst. However, by preparing catalyst...

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