We report on the suitability of water-soluble non-polymeric electrospun cyclodextrin (CD) nanofiber templates by using atomic layer deposition (ALD) to yield metal oxide tubes. To demonstrate this, watersoluble electrospun CD nanofibers were chosen as template to produce metal oxide tubes where we have tested two examples of ALD coatings, namely, Al2O3 and ZnO. After the ALD coating on the CD n...

The interactions between 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([BMIM][TFS]) and nano-Al2O3 are studied using high-pressure infrared spectroscopy. The thickness of the [BMIM][TFS] interfacial layer on the aluminum oxide are adjusted by controlling the number of washes with ethanol. In contrast to the results obtained under ambient pressure, local structures of both the cations a...

This paper describes the results of room temperature joining of TiO2 / SiO2 IRF by sputter deposition with a special emphasis of improvement of adherence at the interface. This multilayer system is designed to shield the infrared energy of solar spectrum by interference reflection. The abrasion resistance of the multilayer stacks was also estimated by the Haze value after the Taber abrasion tes...

The catalytic hydrogenation of p-nitrophenol to p-aminophenol was investigated over alumina supported nickel catalysts prepared by impregnation reduction method and mechanical mixing method. The catalysts were characterized by XRD and FESEM. The results show that the nickel particle diameter of alumina supported nickel prepared by impregnation reduction method (denoted as Ni/Al2O3) is slightly ...

In this study, the physical and electrical characteristics of Al2O3/La2O3/Al2O3/Si stack structures affected by the thickness of an Al2O3 barrier layer between Si substrate and La2O3 layer are investigated after a rapid thermal annealing (RTA) treatment. Time of flight secondary ion mass spectrometry (TOF-SIMS) and X-ray photoelectron spectroscopy (XPS) tests indicate that an Al2O3 barrier laye...

The capacitance and leakage current properties of multilayer La2O3/Al2O3 dielectric stacks and LaAlO3 dielectric film are investigated in this paper. A clear promotion of capacitance properties is observed for multilayer La2O3/Al2O3 stacks after post-deposition annealing (PDA) at 800 °C compared with PDA at 600 °C, which indicated the recombination of defects and dangling bonds performs better ...

Atomic layer deposition (ALD) has been employed to modify the surface of high voltage cathode LiNi0.5Mn1.5O4 by coating ultrathin Al2O3 layer on the electrodes. The ultrathin layer of Al2O3 can suppress the undesirable reactions during cycling, while maintaining the electron and ion conductivity of the electrode. The ALD Al2O3 coated LiNi0.5Mn1.5O4 showed remarkable improvement over bare LiNi0....

The addition of small amounts (2-10 wt %) of SiO2 to γ-Al2O3 increases the temperature of heat treatment necessary for transformation to R-Al2O3 by ∼100 K. We have studied this system using high-temperature solution calorimetry in molten 2PbO‚B2O3 at 1043 K. Our results indicate that the spinel-type Al2O3-SiO2 solid solutions with 2-10 wt % SiO2 are always energetically metastable by 30-35 kJ‚m...

Cu–Zn/γ–Al2O3 catalysts were prepared by the impregnation method. Catalytic activity was evaluated for N2O decomposition in a fixed bed reactor. The fresh and used catalysts were characterized by several techniques such as BET surface area, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The Cu–Zn/γ–Al2O3 catalysts exhibit high activity and stability for N2O decomposition in mi...

The present study was designed to evaluate the hepatotoxicity of aluminium oxide (Al2O3). To achieve this objective, Al2O3 of three different sizes (30nm, 40nm and bulk) was orally administered for 28 days to 9 groups of 10 Wistar rats each, at the dose of 500, 1000 and 2000 mg/Kg/rat. A tenth group of 10 rats received distilled water and served as control. After 28 days of exposure, the animal...